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Spiro, Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları

SYNTHESIS AND THE SPECTRAL INVESTIGATIONS OF SPIRO, ANSA AND BRIDGED DERIVATIVES OF CYCLOCHLOROTRIPHOSPHAZENES

Journal Name:

  • Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi

Publication Year:

  • 2011

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
The reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6 (1) with 2,2-dimethylpropane-1,3-diol yield 9 new cyclophosphazene derivatives. One monospiro, N3P3Cl4[(OCH2)2-CMe2], dispiro, N3P3Cl2[(OCH2)2-CMe2]2 and trisspiro N3P3[(OCH2)2-CMe2]3 derivatives. An ansa, N3P3Cl4[(OCH2)2-CMe2], and a spiro-ansa, N3P3Cl2[(OCH2)2-CMe2]2 isomers. One dangling, N3P3Cl5[(OCH2)2-CMe2OH], one singly-bridged, N3P3Cl5[(OCH2)2-CMe2] N3P3Cl5, one doubly-bridged, N3P3Cl4[(OCH2)2-CMe2]2N3P3Cl4, and one triple-bridged compounds, N3P3Cl3[(OCH2)2- CMe2]2N3P3Cl3 were also isolated. Product types and relative yields were compared with those arising from propane- 1,3-diol. The yields of the spiro, ansa and the bridged products from the reactions of the dimethylpropane-diol system seem to be considerably enhanced relative to those of its unmethylated analogue. The structures of the compounds were determined by using the data obtained from 31P, 1H and 13C N.M.R.
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Abstract (Original Language): 
Bu çalışmada, 2,2-dimetilpropan-1,3-diol ile trimer, N3P3Cl6 (1) reaksiyona sokularak, monospiro, N3P3Cl4[(OCH2)2-CMe2] (3); dispiro, N3P3Cl2[(OCH2)2-CMe2]2 (5), ve tri-spiro, N3P3Cl[(OCH2)2-CMe2]3 (7); dangler N3P3Cl5[(OCH2)2-CMe2OH] (8); mono anza, N3P3Cl4[(OCH2)2-CMe2] (8) ve spiro-anza N3P3Cl2[(OCH2)2-CMe2]2 (6) izomerleri; mono-, N3P3Cl5[(OCH2)2-CMe2]N3P3Cl5 (9); di-, N3P3Cl4[(OCH2)2-CMe2]2N3P3Cl4 (10) ve tri-bino, N3P3Cl3[(OCH2)2-CMe2]3N3P3Cl3 (11) türevlerinden oluşan 9 adet yeni siklofosfazen bileşiği elde edilmiştir. Ürünlerin türü ve oranları, propan-1,3-diol reaksiyon sistemi ile karşılaştırılmıştır. 2,2-dimetil-propan-1,3-diol’dan elde edilen bileşik türleri ve oranları metil grubu taşımayan analoglara göre önemli ölçüde artmıştır. Elde edilen bileşiklerin yapıları 31P, 1H ve 13C NMR spectrumları verilerinden faydalanılarak karakterize edilmiştir.
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  • Turkish

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