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Pinus brutia Ten. (Kızılçam) Kozalak ve Yaprak Biyomasının Boya Biyosorpsiyon/Desorpsiyon Potansiyeli

Dye Biosorption/Desorption Potential of Pinus brutia Ten. (Red pine) Cone and Leaf Biomass

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Abstract (2. Language): 
The regeneration and reuse of biosorbent is quite important in order to make the biosorption process more economical. Desorption studies were performed for elucidating the mechanism of biosorption case, recovery of biosorbent and reuse of biosorbent at biosorption process. Selection of an appropriate eluent is crucial for successful regeneration. A successful desorption process requires the selection of a proper desorbent, which depends on the type of biosorbent and the mechanism of biosorption. The selected desorbents should be effective, cheap and harmless. In this study, dilute (0.1 M) HCl and NaOH solutions were employed for desorption of Basic Red 46 and Acid Yellow 220 dyes biosorbed by the cone and leaf biosorbents of red pine from the biosorbent surfaces. In order to evaluate the reuse potential of biosorbents at the dye biosorption, consecutive biosorption/desorption cycles were repeated three times with the same biosorbent. The minimum dye desorption from the cone and leaf biosorbents for Basic Red 46 by using 0.1 M HCl was defined as %90.88 and %95.99, respectively. For Acid Yellow 220, the minimum dye desorption from the cone and leaf biosorbents by employing 0.1 M NaOH was found as %88.37 and %86.79, respectively. The results displayed that these biosorbents as economically could be repeatedly used in the dye biosorption studies.
Abstract (Original Language): 
Biyosorbent rejenerasyonu ve tekrar kullanımı, biyosorpsiyon prosesini daha ekonomik hale getirmek için oldukça önemlidir. Desorpsiyon çalışmaları, biyosorpsiyon olayının mekanizmasının ortaya konulması, biyosorbentin geri kazanımı ve tekrar biyosorpsiyon prosesinde kullanımı için yapılmaktadır. Başarılı bir desorpsiyon işlemi, biyosorbentin çeşidine ve biyosorpsiyon mekanizmasına göre değişen uygun bir desorbent seçimini gerektirmektedir. Seçilen desorbentler etkili, ucuz ve zararsız olmalıdır. Bu çalışmada, kızılçam kozalak ve yaprak biyosorbentleri tarafından biyosorplanan Basic Red 46 ve Acid Yellow 220 boyalarının biyosorbent yüzeylerinden desorpsiyonu için seyreltik (0,1 M) HCl ve NaOH çözeltileri kullanılmıştır. Biyosorbentlerin boya biyosorpsiyonunda yeniden kullanım potansiyellerini değerlendirmek için ardışık biyosorpsiyon/desorpsiyon döngüsü aynı biyosorbentle üç kez tekrarlanmıştır. 0,1 M HCl kullanımı ile Basic Red 46 boyasının kozalak ve yaprak biyosorbentlerinden en düşük boya desorpsiyonu sırası ile %90,88 ve %95,99 olarak belirlenmiştir. 0,1 M NaOH kullanımı ile Acid Yellow 220 boyası için kozalak ve yaprak biyosorbentlerinden en düşük boya desorpsiyonu sırası ile %88,37 ve %86,79 olarak bulunmuştur. Sonuçlar, bu biyosorbentlerin ekonomik bir şekilde boya biyosorpsiyon çalışmalarında tekrar tekrar kullanılabileceğini göstermiştir.
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REFERENCES

References: 

Aksu, Z., 2005. Application of biosorption for the
removal of organic pollutants: a review. Process
Biochem. 40:997-1026.
Aravindhan, R., Rao, J.R., Nair, B.U., 2007. Removal of
basic yellow dye from aqueous solution by sorption
on green alga Caulerpa scalpelliformis. J. Hazard.
Mater. 142:68-76.
Barka, N., Abdennouri, M., El Makhfouk, M., 2011.
Removal of Methylene Blue and Eriochrome Black T
from aqueous solutions by biosorption on Scolymus
hispanicus L.: Kinetics, equilibrium and
thermodynamics. J. Taiwan Inst. Chem. E. 42:320-326.
Bayramoğlu, G., Çelik, G., Arıca, M.Y., 2006. Studies on
accumulation of uranium by fungus Lentinus
sajorcaju. J. Hazard. Mater. 136:343-351.
KSÜ Doğa Bil. Derg., 17(3), 2014
KSU J. Nat. Sci., 17(3), 2014
25 Araştırma Makalesi
Research Article
Bello, O.S., Adelaide, O.M., Hammed, M.A., Popoola,
O.A.M., 2010. Kinetic and equilibrium studies of
methylene blue removal from aqueous solution by
adsorption on treated sawdust. Macedonian J. Chem.
Eng. 29:77-85.
Blázquez, G., Martín-Lara, M.A., Dionisio-Ruiz, E.,
Tenorio, G., Calero, M., 2012. Copper biosorption by
pine cone shell and thermal decomposition study of the
exhausted biosorbent. J. Ind. Eng. Chem. 18:1741-1750.
Bozanta, E., Ökmen G., 2011. Biyosorpsiyon ve
mikroorganizmalar. Türk Bil. Der. Derg. 4:69-77.
Cheng, W., Wang, S.G., Lu, L., Gong, W.X., Liu, X.W.,
Gao, B.Y., Zhang, H.Y., 2008. Removal of malachite
green (MG) from aqueous solutions by native and
heat-treated anaerobic granular sludge. Biochem. Eng.
J. 39:538-546.
Couto, S.R., 2009. Dye removal by immobilised fungi.
Biotechnol. Adv. 27:227-235.
Dawood, S., Sen, T.K., 2012. Removal of anionic dye
Congo red from aqueous solution by raw pine and
acid-treated pine cone powder as adsorbent:
Equilibrium, thermodynamic, kinetics, mechanism
and process design. Water Res. 46:1933-1946.
Ertaş, M., Acemioğlu, B., Alma, M.H., Usta, M., 2010.
Removal of methylene blue from aqueous solution
using cotton stalk, cotton waste and cotton dust. J.
Hazard. Mater. 183:421-427.
Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman,
A.L., 2010. Effectiveness of Cupressus sempervirens
cones as biosorbent for the removal of basic dyes
from aqueous solutions in batch and dynamic modes.
Bioresour. Technol. 101:9500-9507.
Ferrero, F., 2007. Dye removal by low cost adsorbents:
hazelnut shells in comparison with wood sawdust. J.
Hazard. Mater. 142:144-152.
Gündoğdu, A., Özdeş, D., Duran, C., Bulut, V.N.,
Soylak, M., Şentürk, H.B., 2009. Biosorption of
Pb(II) ions from aqueous solution by pine bark (Pinus
brutia Ten.). Chem. Eng. J. 153:62-69.
Gupta, V.K., Suhas, 2009. Application of low-cost
adsorbents for dye removal - A review. J. Environ.
Manage. 90:2313-2342.
Hai, F.I., Yamamoto, K., Fukushi, K., 2007. Hybrid
treatment systems for dye wastewater. Crit. Rev. Env.
Sci. Technol. 37:315-377.
Hameed, B.H., 2009. Grass waste: A novel sorbent for
the removal of basic dye from aqueous solution. J.
Hazard. Mater. 166:233-238.
Hamutoğlu, R., Dinçsoy, A.B., Cansaran-Duman, D.,
Aras, S., 2012. Biyosorpsiyon, adsorpsiyon ve
fitoremediasyon yöntemleri ve uygulamaları. Türk
Hij. Den. Biyol. Derg. 69:235-53.
Han, R., Ding, D., Xu, Y., Zou, W., Wang, Y., Li, Y.,
Zou, L., 2008. Use of rice husk for the adsorption of
congo red from aqueous solution in column mode.
Bioresour. Technol. 99:2938-2946.
Husain, Q., 2006. Potential applications of the
oxidoreductive enzymes in the decolorization and
detoxification of textile and other synthetic dyes from
polluted water: a review. Crit. Rev. Biotechnol.
26:201-221.
İçgen, Y., Kaya, Z., Çengel, B., Velioğlu, E., Öztürk, H.,
Önde, S., 2006. Potential impact of forest management
and tree improvement on genetic diversity of Turkish
red pine (Pinus brutia Ten.) plantations in Turkey.
Forest Ecol. Manage. 225:328-336.
Karagöz, G., Demirci, M., 2012. Forestry property of
Turkey, General Directorate of Forestry, No: 85,
Ankara.
Lima, E.C., Royer, B., Vaghetti, J.C.P., Simon, N.M., DA
Cunha, B.M., Pavan, F.A., Benvenutti, E.V., Veses,
R.C., Airoldi, C., 2008. Application of Brazilian-pine
fruit coat as a biosorbent to removal of reactive red
194 textile dye from aqueous solution, Kinetics and
equilibrium study. J. Hazard. Mater. 155:536-550.
Liu, R., Zhang, B., Mei, D., Zhang, H., Liu, J., 2011.
Adsorption of methyl violet from aqueous solution by
halloysite nanotubes. Desalination 268:111-116.
Mahmoodi, N.M., Hayati, B., Arami, M., Lan, C., 2011.
Adsorption of textile dyes on pine cone from colored
wastewater: kinetic, equilibrium and thermodynamic
studies. Desalination 268:117-125.
Mittal, A., Mittal, J., Malviya, A., Gupta, V.K., 2010.
Removal and recovery of Chrysoidine Y from
aqueous solutions by waste materials. J. Colloid
Interface Sci. 344:497-507.
Ofomaja, A.E., Naidoo, E.B., 2011. Biosorption of copper
from aqueous solution by chemically activated pine
cone: A kinetic study. Chem. Eng. J. 175:260-270.
Ofomaja, A.E., Naidoo, E.B., Modise, S.J., 2009.
Removal of copper (II) from aqueous solution by pine
and base modified pine cone powder as biosorbent J.
Hazard. Mater. 168:909-917.
Ofomaja, A.E., Pholosi, A., Naidoo, E.B., 2013. Kinetics
and competitive modeling of cesium biosortion onto
chemically modified pine cone powder. J. Taiwan Ins.
Chem. Eng. 44:943-951.
Rauf, M.A., Qadri, S.M., Ashraf, S., Al-Mansoori, K.M.,
2009. Adsorption studies of Toluidine Blue from
aqueous solutions onto gypsum. Chem. Eng. J.
150:90-95.
Sen, T.K., Afroze, S., Ang, H.M., 2011. Equilibrium,
kinetics and mechanism of removal of methylene blue
from aqueous solution by adsorption onto pine cone
biomass of Pinus radiata. Water Air Soil Pollut.
218:499-515.
Vijayaraghavan, K., Yun, Y.S., 2008b. Biosorption of
C.I. Reactive Black 5 from aqueous solution using
acid-treated biomass of brown seaweed Laminaria
sp.. Dyes Pigments 76:726-732.

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