Bazı Metal-Oksinat Komplekslerinin Ardışık TLC/IR Sistemi ile Ayrılma ve Tanı Olanaklarının Araştırılması

Investigation of qualitative separation and identification possibilities of some metal-oxinate complexes by combination of TLC and IR-spectroscopy has been aimed. Optimum separation conditions of these metal complexes and the reproducibilities of their retention factors, Rf have been investigated onhomemade TLC plates. Four different stationary phases with a serial of silica gel origin and solvent or solvent systems, which have medium intensity polarity were used for chromatographic separation that substantially are based on adsorption. Rf values of metal complexes were determined by making one-dimensional repetitive developments on TLC plates for each of combinations of adsorbents and solvents. Standard deviations and relative standard deviations for the retention factor values for five repetitive measurement series have been determined. For the metal complexes having the overlapped bands or retention factors which is close to each other, their IR-spectra have been obtained for their precise identifications after they are pre-concentrated at the end of wick stick. It could qualitatively be identified the complexes by the aid of specific absorbing bands on the IR spectra. It has been evaluated that these specific absorbing bands will be able to use as reference spectral bands in the possible quantitative studies. Additionally, It has been concluded that it will partially be made an effective and successful qualitative and semi-quantitative analysis for some oxinate complexes by using IR-spectrophotometer as a TLC detector.