You are here

Home » Content

CRYSTALLINE STARCH CITRATE BIOPOLYMER NANORODS AS POTENTIAL STABILIZERS IN NANO AND MICRO EMULSIONS

Journal Name:

  • Journal of The Turkish Chemical Society, Section B: Chemical Engineering

Publication Year:

  • 2017

Key Words:

Author NameUniversity of Author
Abstract (2. Language): 
The area of green chemistry which involves the synthesis of biodegradable polymers with better stabilizing properties is fast-developing. Starch biopolymer was citrate modified and converted to crystalline nanorods through green methods and was fully characterized using the fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA). The crystalline starch citrate showed better morphological and thermal stability properties than the ordinary and modified normal starch which has not been converted to nano form. The TGA result revealed a single step thermal degradation at 240 to 410 °C and percentage weight loss of about 89%. The SEM and TEM also confirmed the synthesis of rod-like or cylindrical nanoparticles with little or no aggregation. This property coupled with the thermal stability makes starch citrate nanoparticles a good stabilizer for nano and micro emulsions.
Bookmark/Search this post with
FULL TEXT (PDF): 
PDF icon arastirmax-crystalline-starch-citrate-biopolymer-nanorods-potential-stabilizers-nano-and-micro-emulsions.pdf
  • 2
191
200
  • English

REFERENCES

References: 

1. Ma X, Jian R, Chang PR, Yu J. Fabrication and Characterization of Citric Acid-Modified Starch Nanoparticles/Plasticized-Starch Composites. Biomacromolecules. 2008 Nov 10;9(11):3314–20.
2. Yu J, Wang N, Ma X. Fabrication and Characterization of Poly(lactic acid)/Acetyl Tributyl Citrate/Carbon Black as Conductive Polymer Composites. Biomacromolecules. 2008 Mar;9(3):1050–7.
3. Santander-Ortega MJ, Csaba N, Alonso MJ, Ortega-Vinuesa JL, Bastos-González D. Stability and physicochemical characteristics of PLGA, PLGA:poloxamer and PLGA:poloxamine blend nanoparticles. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2007 Mar;296(1–3):132–40.
4. Santander-Ortega MJ, Stauner T, Loretz B, Ortega-Vinuesa JL, Bastos-González D, Wenz G, et al. Nanoparticles made from novel starch derivatives for transdermal drug delivery. Journal of Controlled Release. 2010 Jan 4;141(1):85–92.
5. López-León T, Elaïssari A, Ortega-Vinuesa JL, Bastos-González D. Hofmeister Effects on Poly(NIPAM) Microgel Particles: Macroscopic Evidence of Ion Adsorption and Changes in Water Structure. ChemPhysChem. 2007 Jan 8;8(1):148–56.
6. Chivrac F, Pollet E, Schmutz M, Avérous L. New Approach to Elaborate Exfoliated Starch-Based Nanobiocomposites. Biomacromolecules. 2008 Mar;9(3):896–900.
7. Enturi V, Chowdary BY, Chowdary K. Enhancement of dissolution rate and formulation development of irbesartan tablets by employing starch phosphate: A new modified starch. Asian Journal of Pharmaceutics (AJP): Free full text articles from Asian J Pharm. 2014;8(3).
8. Jivraj M, Martini LG, Thomson CM. An overview of the different excipients useful for the direct compression of tablets. Pharmaceutical Science & Technology Today. 2000 Feb;3(2):58–63.
9. Wepner B, Berghofer E, Miesenberger E, Tiefenbacher K, N. K. Ng P. Citrate Starch — Application as Resistant Starch in Different Food Systems. Starch - Stärke. 1999 Oct;51(10):354–61.
10. Chin SF, Pang SC, Tay SH. Size controlled synthesis of starch nanoparticles by a simple nanoprecipitation method. Carbohydrate Polymers. 2011 Oct;86(4):1817–9.
11. Pang SC, Chin SF, Tay SH, Tchong FM. Starch–maleate–polyvinyl alcohol hydrogels with controllable swelling behaviors. Carbohydrate Polymers. 2011 Feb;84(1):424–9.
12. Kim J-Y, Lim S-T. Preparation of nano-sized starch particles by complex formation with n-butanol. Carbohydrate Polymers. 2009 Mar;76(1):110–6.
Saliu et al., JOTCSB. 2017; 1(2): 191-200. RESEARCH ARTICLE
199
13. Loftsson T, Másson M, Brewster ME. Self-Association of Cyclodextrins and Cyclodextrin Complexes. Journal of Pharmaceutical Sciences. 2004 May;93(5):1091–9.
14. Rondeau-Mouro C, Bail PL, Buléon A. Structural investigation of amylose complexes with small ligands: inter- or intra-helical associations? International Journal of Biological Macromolecules. 2004 Oct;34(5):251–7.
15. Shi A, Li D, Wang L, Li B, Adhikari B. Preparation of starch-based nanoparticles through high-pressure homogenization and miniemulsion cross-linking: Influence of various process parameters on particle size and stability. Carbohydrate Polymers. 2011 Feb 1;83(4):1604–10.
16. Veiseh O, Gunn JW, Zhang M. Design and fabrication of magnetic nanoparticles for targeted drug delivery and imaging. Advanced Drug Delivery Reviews. 2010 Mar;62(3):284–304.
17. Demitri C, Del Sole R, Scalera F, Sannino A, Vasapollo G, Maffezzoli A, et al. Novel superabsorbent cellulose-based hydrogels crosslinked with citric acid. Journal of Applied Polymer Science. 2008 Nov 15;110(4):2453–60.
18. Fujioka R, Tanaka Y, Yoshimura T. Synthesis and properties of superabsorbent hydrogels based on guar gum and succinic anhydride. Journal of Applied Polymer Science. 2009 Oct 5;114(1):612–6.
19. Salam A, Pawlak JJ, Venditti RA, El-tahlawy K. Synthesis and Characterization of Starch Citrate−Chitosan Foam with Superior Water and Saline Absorbance Properties. Biomacromolecules. 2010 Jun 14;11(6):1453–9.
20. Chang PR, Yu J, Ma X. Preparation of porous starch and its use as a structure-directing agent for production of porous zinc oxide. Carbohydrate Polymers. 2011 Jan;83(2):1016–9.
21. Abbas S, Bashari M, Akhtar W, Li WW, Zhang X. Process optimization of ultrasound-assisted curcumin nanoemulsions stabilized by OSA-modified starch. Ultrasonics Sonochemistry. 2014 Jul;21(4):1265–74.
22. Karadag A, Yang X, Ozcelik B, Huang Q. Optimization of Preparation Conditions for Quercetin Nanoemulsions Using Response Surface Methodology. Journal of Agricultural and Food Chemistry. 2013 Mar 6;61(9):2130–9.
23. Manoi K, Rizvi SSH. Physicochemical characteristics of phosphorylated cross-linked starch produced by reactive supercritical fluid extrusion. Carbohydrate Polymers. 2010 Jul;81(3):687–94.
24. Ghosh V, Mukherjee A, Chandrasekaran N. Ultrasonic emulsification of food-grade nanoemulsion formulation and evaluation of its bactericidal activity. Ultrasonics Sonochemistry. 2013 Jan;20(1):338–44.

Thank you for copying data from http://www.arastirmax.com