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Determination of Ion Concentrations and Heavy Metals in the Air Particulates of an Industrial Area

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Abstract (2. Language): 
This study deals with the determination of heavy metals, anions and cations in atmospheric aerosols at four heavily polluted sites in Samsun city, Turkey. The anions (Cl-, Br-, NO3- and NO2-) and cations (Na+, K+ and NH4+) in the samples were determined by ion chromatography using a potentiometric detector with ion selective electrodes. Flame and graphite-furnace Atomic Absorption Spectrometer was used for the determination of Pb, Cu, Zn and Fe. The average values of Cl-, NO3-, NO2-, Br-, Na+, K+ and NH4+ concentrations in the samples were 4.58±1.30, 7.42±1.32, 0.86±0.10, 0.28±0.05, 0.77±0.13, 0.72±0.06, and 1.08±0.09 μg/m3 respectively. The average values of Zn, Cu, Fe and Pb concentrations in the samples were 2.32±0.21, 1.71±0.14, 2.29±0.18, and 2.46±0.22 μg/m3 respectively.
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REFERENCES

References: 

Adriano, DC. 1986. Trace elements in the terrestrial environment. New York press, Springer-Verlag.
Avila, A. 1996. Time trends in the precipitation chemistry at a mountain site in northeastern Spain for the period 1983-1994. Atmos. Environ., 30: 1363-1373.
Cabada JC., Rees, S., Takahama, S., Khlystov, A., Pandis, SN., Davidson, CI., Robinson, AL. 2004. Mass size distributions and size resolved chemical composition of fine particulate matter at the Pittsburgh supersite, Atmos. Environ., 38: 3127-3141.
Dams, R. 1992. Nuclear Activation techniques for the determination of trace elements in atmospheric aerosols, particulates and sludge samples. Pure Appl. Chem. 64: 991-1014
Eatough, NL., McGregor, S., Lewis, EA., Eatough, DJ., Huang, AA., Ellis, EC. 1988. Comparison of six denuder methods and a filter pack for the collection of ambient HNO3 (g), HNO2 (g), and SO2 (g) in the 1985 NSMC study. Atmos. Environ., 22: 1601-1618.
El-Ghandour, MF., Abdel Salim, MS., Hindy, KT., Kamel, MM. 1982. Studies on air pollution from construction plants in the Helwan area. III. Alkali, earth alkali and heavy metal constituents of dust-fall. Environ. Pollut. Ser. B4: 303-313.
Hall, JS., Wolf, EW. 1998. Causes of seasonal and daily variations in aerosol sea-salt concentrations at a coastal Antarctic station. Atmos. Environ., 32: 3669-3677.
Henning, S., Weingartner, E., Schwikowski, M., Gaggeler, HW., Gehring, R., Hinz, KP., Trimborn, A., Spengler, B., Baltensperger, U. 2003. Seasonal variation of water-soluble ions of the aerosol at the high-alpine site Jungfraujoch (3589 m asl). J. Geophys. Res., 18: 8–10.
Hong, S., Kang, CY., Kang, J. 1999. Lichenbiomonitoring for the detection of local heavy metal pollution around King Sejong Station, King George Island, Antarctica. Korean J. Polar Res., 10: 17-24.
Hu, GP., Balasubramanian, R., Wu, CD. 2003. Chemical characterization of rainwaterat Singapore. Chemosphere, 51: 747-755.
Isildak, I., 1999. Potentiometric Detection of Anions Seperated by Ion Chromatography Using all Solid-State Contact PVC Matrix Membrane Electrode. Chromatographia, 49: 338-342
Isildak, I., Asan, A. 1999. Simultaneous detection of Anions and Cations Using all Solid-State Contact PVC Membrane Anion and Cation-Selective Electrodes as Detectors in Single Column Ion Chromatography. Talanta, 48: 967-978.
Isıldak, I., Covington, AK. 1993. Ion-Selective Electrode Potentiometric Detection in Ion Chromatography. Electroanalysis, 5: 815-824.
Kim, KH., Lee, M., Lee, G., Kim, YP., Youn, YH., Oh, JM. 2002. Observations of aerosol-bound ionic compositions at Cheju Island, Korea. Chemosphere, 48: 317-327.
McMichael, AJ., Baghurst, PA., Robertson, EF., Vimpani GV., Wigg, NM. 1985. The port Pirie study: blood lead concentrations in early childhood. Med. J. Aust., 143: 499– 503.
Mello, WZ. 2001. Precipitation chemistry in the coast of the Metropolitan region of Rio de Janeiro Brazil. Environ. Pollut., 114: 235-242.
Mishra, V., Kim, Ki-H., Hong, S., Lee, K. 2004. Aerosol composition and its sources at the king sejong station, antartic peninsula, Atmos. Environ., 38: 4069-4084.
Rizzio, E., Giaveri, G., Gallorini, M. 2000. Some analytical problems encountered for trace elements determination in the airborne particulate matter of urban and rural areas. Sci. Total Environ., 256 : 11– 22.
Watt, J., Thornton, I., Cotter-Howells, J. 1993. Physical evidence suggesting the transfer of soil Pb into young children via hand-to-mouth activity. Appl. Geochem., 2: 269–72.
WHO, 1999. Air Quality Satandarts, For Europe, Regional Office for Europe series, 27, Copenhagen.

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