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EFFECT OF TEMPERATURE ON PROTECTIVE PROPENSITY OF ACACIA NILOTICA ON ACID CORROSION OF COPPER

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Abstract (Original Language): 
The inhibition effect of Acacia nilotica P ethanolic extract on copper corrosion in 0.5N hydrochloric acid has been studied by weight loss method between 303-353K temperatures. The inhibition efficiency increased with increase in concentration of plant extract. The corrosion rate increased with increase in temperature and decreased with increase in concentration of inhibitor compared to blank. The adsorption of inhibitor on Cu metal have been found to obey Langmuir adsorption isotherm. The values of activation energy (Ea), free energy of adsorption (?G ), enthalpy of adsorption (?H), ads and entropy of adsorption (?S) were calculated. The G values indicate that the adsorption of EE P on copper metal surface is physical in nature. Surface analysis (FT- An IR) was also carried out to establish the mechanism of corrosion inhibition on copper corrosion in hydrochloric acid medium.
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REFERENCES

References: 

1.Da-Quan Zhang, Li-Xin Gao, Guo-Ding Zhou, “Inhibition of Copper Corrosion in Aerated Hydrochloric
Acid Solution by Amino-acid Compounds” J. Appl. Electrochem., 35 (2005)1081–1085.
2.Mohammed A. Amin, “Weight loss, polarization, electrochemical impedance spectroscopy, SEM and
EDX studies of the corrosion inhibition of copper in aerated NaCl solutions”, J. Appl. Electrochem.,36,
(2006) 215-226.
3.L. A. Nnanna1, B. N. Onwuagba, I. M. Mejeha, K. B. Okeoma, “Inhibition effects of some plant extracts
on the acid corrosion of aluminium alloy”, Afric. J. Pure. Appl. Chem., 4(1), (2010) 11-16.
4. M. Lebrini, F. Robert, C. Roos, “Alkaloids Extract from Palicourea guianensis Plant as Corrosion
Inhibitor for C38 Steel in 1 M Hydrochloric Acid Medium”, Int. J. Electrochem. Sci., 6, (2011) 847 – 859.
5.K. Barouni, L. Bazzi, R. Salghi, M. Mihit, B. Hammouti, A. Albourine, S. El Issami, “ Some amino acids
as corrosion inhibitors for copper in nitric acid solution” Mater. Lett., 62 (19), (2008) 3325-3327.
6.S. Malviya, S. Rawat, M Verma, A Kharia, “ Preliminary Phytochemical Investigations of Acacia nilotica
Linn Plant”, Current Pharma Research, 1(2), 2011, 91-100.
7.R .Chaubal, A. Tambe, “Isolation of new straight chain compound from Acacia nilotica”, Ind. J. Chem.,
45(B) (2006) 1231-1233.
8.S. Malviya, S. Rawat, A Kharia, M Verma, “Medicinal attributes of Acacia nilotica Linn. - A
comprehensive review on ethnopharmacological claims”, Int. J. PHARMACY & LIFE SCIENCES, 2 (6)
(2011)
9.V. Verma, U. K. Singh, A. K. Sharma, S. Sharma, B. Singh, P. Goyal, R. Singh, “ A Review on Acacia
nilotica Linn. And its ethnobotany, phytochemical and pharmalogical profile”, Int. J. Of pharmaceutical
Reaserch and development, 4 (3) (2012) 251-256.
10.J. Dubey, P. Sharma, A. Chaturvedi, R.K.Upadhyay, “Effect of Temperature on Corrosion Inhibition
Efficiency of Withania Somnifera (Ashwagandha) on Aluminium in HCl Solution”, J. Corros. Sci. Engg.,
13 (1) (2010).
11.2. M. Hazwan Hussin* and M. Jain Kassim, “Thermodynamic characterisation of mild steel corrosion
and inhibition adsorption of Uncaria gambir and catechin in 1 M HCl”, J. Corros. Sci. Engg., 13 (1) (2010).
12.A. Ostovari, S. M. Hoseinien, M. Peikari, S. R. Shadizadeh and S. J. Hashemi; in: “Corrosion inhibition
of mild steel in 1M HCl solutions by heena extract: A comparative study of the inhibition by heena and its
constituents ( Lawsone, Gallic acid, D-Glucose and Tannic acid)”, Corros.sci., 51 (2009)1938.
13.B.C. Smith, Fundamentals of Fourier transform infrared spectroscopy, CRC Press, London, UK (1996).
14.E. A. Noor, “Temperature effects on the corrosion inhibition of mild steel in acidic solution by Aqueous
extract of Fenugreek Leaves”, Int. J. Electrochem. Sci., 2 (2007) 996.
15.A. M. Abdel-Gaber, “Effect of Immersion Time and Temperature on the Inhibition of the Acid Corrosion
of Zinc by Fenugreek Seeds Extract”, Int. J. App. Chem., 3 (3) (2007) 231.
16.I.B. Obot1, N.O. Obi-Egbedi, S.A. Umoren, “Adsorption Characteristics and Corrosion Inhibitive
Properties of Clotrimazole for Aluminium Corrosion in Hydrochloric Acid”, Int. J. Electrochem. Sci., 4,
(2009) 863 – 877.
17.J. Buchweishaija, G.S. Mhinzi, J. Buchweishaija, “Natural Products as a Source of Environmentally
Friendly Corrosion Inhibitors: The Case of Gum Exudate from Acacia seyal var. seyal”, Portug.
Electrochem. Acta, 26 (2008) 257-265.

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