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AĞIR METAL İÇEREN ATIKSU ARITIMINDA KULLANILAN DÜŞÜK MALİYETLİ ADSORBENTLER

LOW-COST ADSORBENTS USED IN HEAVY METAL CONTAMINATED WASTE WATER TREATMENT

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Abstract (2. Language): 
In this review, adsorbents used in wastewater treatment and their technical feasibilities are reviewed. Adsorbents are classified as natural adsorbents, and the adsorbents obtained from industrial and agricultural wastes. They all were compared with each other condensing the metal binding capacities, costs and metal removal performances in waste water treatments. Although commercial activated carbon is widely used in wastewater treatment applications, it has high costs. Instead of activated carbon, we focused on the inexpensive materials like chitosan, zeolite, and clay as natural adsorbents; waste slurry and ash as industrial waste; and, rice husk and coconut shell as agricultural waste. It was shown that these alternative adsorbents had sufficient binding capacity to remove heavy metals from wastewater.
Abstract (Original Language): 
Bu derleme makalede atıksu arıtımında kullanılan adsorbentler ve arıtımdaki teknik uygunlukları incelenmiştir. Adsorbentler; doğal, endüstriyel ve tarımsal atıklardan elde edilen adsorbentler olarak sınıflandırılmıştır. Bu adsorbentler metal bağlama kapasiteleri, maliyetleri ve arıtımda gösterdikleri verimlilik bakımından karşılaştırılmışlardır. Adsorpsiyon işlemlerinde aktif karbon yaygın olarak kullanılmasına rağmen yüksek maliyetlere yol açmaktadır. Aktif karbona alternatif oluşturabilecek, düşük maliyetli kitosan, zeolit, kil gibi doğal adsorbentler; atık çamur, kül gibi endüstriyel atıklar ve pirinç kabuğu, narenciye kabuğu, hindistan cevizi kabuğu gibi tarımsal atıklar üzerinde durulmuş ve bu adsorbentlerin atıksulardan ağır metal gideriminde yeterli bağlama kapasiteleri olduğu görülmüştür.
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REFERENCES

References: 

[1] Sarıkaya Y., “Çevre Sorunları”, A.Ü. Fen Fak., Bilge Yayıncılık, Ankara. 1993.
[2] Tien C., “Adsorbtion Calculations and Modeling”, Department of Chemical Engineering
and Materials Science, Syracuse University, Butterworth-Heinemann, Newton. 1994.
[3] Babel S., Kurniawan T A., “Low- cost adsorbents for heavy metal uptake from
contaminated water”, J. Hazard. Mater., 9, 219-243, 2003.
[4] Rorrer G.L., Way J.D., “Chitosan beeds to remove heavy metal from wastewater”,
Dalwoo-ChitoSan, 2002.
[5] Grant D.C., Skribi M. C., Saha A.K., “Removal of radioactive contaminants from west
valley waste streams using natural zeolites”, Environ. Prog., 6, 104-109, 1987.
[6] Virta R, “USGS Minerals Information”, US Geological Survey Mineral Commodity
Summary, 2002.
[7] Aoki T., Munemori M., “Recovery of chromium (VI) from wastewaters with iron (III)
hydroxide-I: Adsorption mechanism of chromium (VI) on iron (III) hdroxide”, Water
Res., 16, 793-796, 1982.
[8] Jha I.N., Iyengar L., Rao S.P., “Removal of cadmium using chitosan”, J. Environ. Eng,.
114, 962-974, 1988.
[9] McKay G., Blair H.S., Findon A., “Equilibrium studies for the sorption of metal-ions onto
chitosan”, Ind. Chem., 28A, 356-360, 1989.
[10] Peniche-Covas C., Alvarez L.W., Arguella-Monal W., J. Appl. Polym. Sci., 46,1147-
1150, 1991.
[11] Zamzow M. J., Eichbaum B.R., “Removal of heavy-metals and other cations from waste
water using zeolits”, Sep. Sci. Technol., 25, 1555-1569, 1990.
[12] Malliou E., Malamis M., Sakellarides P.O., “Lead and cadmium removal by ionexchange”, Water Sci. Technol., 25, 133-138, 1992.
[13] Brigatti M.F., Campana G., Medici L., et al., “The influence of layer charge on Zn2+and
Pb2+ sorption by smectites”, Clays Clay Miner, 31, 477-483, 1996.
[14] Srivastava S.K., Tyagi R., Pal N., “Studies on the removal of some toxic metal-ions. 2.
Removal of lead and cadmium by montmorillonite and kaolinite”, Environ. Technol.
Lett., 10, 275-282, 1989.
[15] Undaybeytia T., Morillo E., Maqueda C., “Adsorption of Cd and Zn on montmorillonite
in the presence of a cationic pesticide”, Clays Clay Miner, 31, 485-490, 1996.
[16] Singh V. N., Environ. Technol. Lett., 9,1153-1162, 1988.
[17] Yadava K.P., Tyagi B.S., Singh V. N., J. Chem. Biotechnol. 51, 47-60, 1991.
[18] Chantawong V., Harvey N. W., Bashkin V.N., “Comparison of heavy metal adsorptions
by thai kaolin and ballclay”, Asian J. Energy Anviron., 1, 33-48, 2001.
[19] Khan S.A., Rehman R., Khan M.A., “Adsorption of strontium (II) on bentonite”, Waste
Manage., 15, 271-282, 1995.
[20] Mellah A., Chegrouche S., “The removal of zinc from aqueous solution by natural
bentonite”, Water Res., 31, 621-629, 1997.
[21] Naseem R., Tahir S.S., “Removal of Pb (II) from aqueous/acidic solutions by using
bentonite as an adsorbent”, Water Res., 35, 3982-3986, 2001.
[22] Sharma D.C., Forster C.F., “Removal of hexavalent chromium using sphagnum mass
peat”, Water Res., 27, 1201-1208, 1993.
[23] Chen X.-H., Gosset T. ,Thevenot D.R., “Batch copper ion binding and exchange
properties of peat” Water Res., 24, 1463-1471, 1990.
[24] Sharma D.C., Forster C.F., “A preliminary examination into the adsorption of hexavalent
chromium using low-cost adsorbents”, Process Biochem., 30, 293-298, 1994.
[25] Bhattacharya A.K., Venkobachar C., “Removal of cadmium (II) by low-cost adsorbents”,
J. Environ. Eng., 110, 110-122, 1984.
[26] Gupta G. S., Prasad G., Singh V. N., Water Res., 24, 45-50, 1990.
[27] Gupta D.C., Tiwari U.C., Ind. J. Environ. Health, 27, 205-215, 1985.
[28] Srivastava S.K., Bhattacharjee G., Tygai R., et. al., “Studies on the removal of some toxic
metal-ions from aqueous-solutions and industrial-waste. 1. (Removal of lead and
cadmium by hydrous iron and aluminum-oxide)”, Environ. Technol. Letter., 9, 1173-
1185, 1988.
[29] Lui M. _H, Hong H.-Z., Zhang X.-S., et. al., “Removal and recovery of chromium (III)
from aqueous solutions by a spheroidal cellulose adsorbent”, Water Environ. Res., 73,
322-328, 2001.
[30] Panday K.K., Prasad G., Singh V.N., “Copper (II) removal from aqueous solutions by fly
ash”, Water Res., 19, 869-873, 1985.
[31] Panday K.K., Prasad G., Singh V.N., “Removal of Cr(VI) from aqueous solutions by
adsorption on fly-ash wollastonite”, J. Chem. Technol. Biotechnol., 34A, 367-374, 1984.
[32] Sen A.K., Arnab K.D., “Adsorption of mercury on coal fly-ash”, Water Res., 21, 885-887,
1987.
[33] Namasivayam C., Ranganathan K., “Waste Fe (III)/Cr(III) hydroxide as adsorbent for the
removal of Cr(VI) from aqueous solution and chromium plating industry wastewater”,
Environ. Pollut., 82, 255-261, 1992.
[34] Srivastava S.K., Tyagi R., N Pant., “Adsorption of heavy metal ions on carbonaceous
material developed from the waste slurry generated in local fertilizer plants”, Water Res.,
23, 1161-1165, 1989.
[35] Lee S.M., Davis A.P., “Removal of Cu (II) and Cd (II) from aqueous solution by seafood
processing waste sludge”, Water Res., 35, 534-540, 2001.
[36] Srivastava S.K., Singh A.K., Sharma A., “Studies on the uptake of lead and zinc by lignin
obtained from liquor-a paper- industry waste material”, Environ Technol., 15, 353-361,
1994.
[37] Dimitrova S.V., “Metal sorption on blast-furnace slag”, Water Res., 30, 228-232, 1996.
[38] Ajmal M., Khan A.H. ,Ahmad S. Ahmad A, “Role of sawdust in the removal of copper
(II) from industrial wastes”, Water Res., 32, 3085-3091, 1998.
[39] Taty-Costodes V. C., Fauduet H., Porte C., Delacroix A., “Removal of Cd (II) and Pb
ions, from aqueous solutions, by adsorption onto sawdust of Pinus sylvestris”, J. Hazar.
Mater., B 105, 121-142, 2003.
[40] Shukla S. S., Yu L. J., Dorris K. L. ,Shukla A., “Removal of nickel from aqueous
solutions by sawdust”, J. Hazar. Mater, B 21, 243-246, 2005.
[41] Pradhan J., Das S.N., Thakur R.S., “Adsorption of hexavalent chromium from aqueous
solution by using activated red mud”, J. Colloid İnterf. Sci., 217, 137-141, 1999.
[42] Hamadi N.K., Chen X.-D., Farid M.M., “Adsorption kinetics for the removal of
chromium (VI) from aqueous solution by adsorbents derived from used tyres and
sawdust”, Chem.Eng. J., 84, 95-105, 2001.
[43] Gupta V.K., Morhan D., Sharma S., et. al., The Environmentalist, 19,129-136, 1999.
[44] Tare V., Chaudhari S., Jawed M., “Comparative-evaluation of soluble and insoluble
xanthate process for heavy-metal removal from wastewaters”, Water Sci. Technol., 26,
237-246, 1992.
[45] Srinivasan K. ,Balasubramanian N., Ramakhrisna T.V., Indian J. Environ. Health, 30,
376-387, 1988.
[46] Saeed A., Iqbal M., Akhtar W., “ Removal and recovery of lead(II) from single and
multimetal (Cd, Cu, Ni, Zn) solutions by crop milling waste (black gram husk)”, J. Hazar.
Mater , B 117, 65-73, 2005.
[47] Alaerts G.J., Jitjatuturunt V., Kelderman P., “Use of coconut shell-based activated carbon
for chromium”, Water Sci. Technol., 21, 1701-1704, 1989.
[48] Meunier N., Laroulandie J., Blais J. F., Tyagi R.D., “ Cocoa shells for heavy metal
removal from acidic solutions”, Bioresource Technology, 90, 255-263, 2003.
[49] Ajmal M., Rao R.A.K., Ahmad R., et.al., “Adsorption studies on Citrus reticulata (fruit
peel of orange): Removal and recovery of Ni (II) from electroplating wastewater”, J. of
Hazar. Mater., 79, 117-131, 2000.
[50] Huang C.-P., Blankkenship D.W., Water Res., 18 (1984) 37-46
[51] Netzer A., Hughes, D.E., “Adsorption of copper, lead and cobalt by activated carbon”,
Water Res., 18, 927-933, 1984.
[52] Reed B.E., Arunachalam S., “Use of granuler activated carbon columns for lead
removal”, J. Environ. Eng., 120, 416-436, 1994.
[53] Candela M.P., Martinez J.M., Macia R.T., “Chromium (VI) removal with activated
carbons”, Water Res., 29, 2174-2180, 1995.
[54] Mohanty K., Jha M., Meikap B. C:, Biswas M.N., “Removal of chromium (VI) from
dilute aqueous solutions by activated carbon developed from Terminalia arjuna nuts
activated with zinc chloride”, Chemical Engineering Science, 60, 3049-3059, 2003.
[55] Lin T.-F., Wu J.-K., Water Res., 35, 2049-2057, 2000.
[56] Bang S., Patel M., Lippincott L., Meng X., “Removal of arsenic from groundwater by
granuler titanium dioxide adsorbent”, Chemosphere, 60, 389-397, 2005.
[57] Chuang C.L., Fan M., Xu M., Brown R.C., Sung S., Saha B., Huang C.P., “Adsorption of
arsenic (V) by activated carbon prepared from oat hulls”, Chemosphere, 2005, In press.

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