You are here

Home » Content

ENDÜSTRİYEL ATIKSULARIN ARITIMINDA İLERİ OKSİDASYON PROSESLERİNİN UYGULANABİLİRLİĞİNİN ARAŞTIRILMASI

Investigation of Applicability of Advanced Oxidation Processes for Industrial Wastewater Treatment

Journal Name:

  • Uludağ Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi

Publication Year:

  • 2008

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
The theories of advanced oxidation processes (AOPs) used in industrial wastewater treatment such as ozone at high pH (pH>11), Ozone/Hydrogen Peroxide, Ozone/UV, Hydrojen Peroxide/UV, O3/H2O2/UV and Vacuum Ultraviolet (VUV) processes have been given and the treatability studies of industrial wastewater by these methods have been examined extensively in this study. COD, TOC, colour and phenol removal efficiencies have been obtained 87-99%, 80-95%, 91-100%, 90-100%, respectively in the example studies. Finally, it has been shown that advanced oxidation processes treated industrial wastewater by successfully and reduced the pollutant quantities until discharge criterias according to removal efficiencies obtained from these studies. Although the treatment efficiency of advanced oxidation processes is very high, more treatment cost of AOPs can be determine a disavantage.
Bookmark/Search this post with
Abstract (Original Language): 
Bu çalışmada, endüstriyel atıksuların arıtımında kullanılan ileri oksidasyon proseslerinden, Yüksek pH’ta Ozonlama (pH>11), Ozon–Hidrojen Peroksit, Ozon–UV, Hidrojen Peroksit–UV, O3/H2O2/UV ve Vakum Ultraviyole (VUV) Proseslerinin teorisi verilmiş ve bu proseslerle çeşitli endüstriyel atıksuların arıtılabilirliği üzerine yapılmış olan çalışmalar kapsamlı bir şekilde incelenmiştir. Atıksu arıtımının ileri oksidasyon prosesleriyle (İOP) yapıldığı çalışmalarda, KOİ, TOC, renk ve fenol giderim verimleri sırasıyla, %87-99, %80-95, %91-100, %90-100 oranlarında elde edilmiştir. Sonuç olarak yapılan uygulamalarda elde edilen giderim verimleri, İOP’nin endüstriyel atıksuların arıtımını başarıyla gerçekleştirdiğini ve kirletici miktarlarını deşarj kriterlerine indirdiğini göstermiştir. Arıtma veriminin yüksek olmasına karşın, İOP’nin arıtma maliyetinin yüksek olması bir dezavantaj olarak belirtilebilir.
FULL TEXT (PDF): 
PDF icon arastirmax-endustriyel-atiksularin-aritiminda-ileri-oksidasyon-proseslerinin-uygulanabilirliginin-arastirilmasi.pdf
  • 1
67-80
  • Turkish

REFERENCES

References: 

1. Akal Solmaz, S. K., Birgül, A., Üstün, G. E. and Yonar, T. (2006) Colour and COD Removal from Textile
Effluent by Coagulation and Advanced Oxidation Processes, Color. Technol., 122, 102-109.
2. Alapi T. and Dombi, A. (2007) Comparative Study of the UV and UV/VUV-Induced Photolysis of Phenol in
Aqueous Solution, Journal of Photochemistry and Photobiology A: Chemistry, 188, 409-418.
3. Aleboyeh, A., Olya, M.E. and Aleboyeh, H. (2007) Electrical Energy Determination for an Azo Dye
Decolorization and Mineralization by UV/H2O2 Advanced Oxidation Process, Chemical Engineering
Journal, 137(3), 518-524.
4. Anonim, (1998) Advanced Photochemical Oxidation Process, Handbook, US. EPA, Washington, DC.
5. Arslan, I. (2000) Treatment of Reactive Dye-Bath Effluents by Heterogeneous and Homogeneous Advanced
Oxidation Processes, Submitted to the Institute of Environmental Sciences in partial fulfillment of the
requirements for the degree of Doctor of Philosophy in Environmental Technology, Bogazici University.
6. Arslan, I., Akmehmet Balcioglu, I. and Bahnemann, D.W. (2000) Advanced Chemical Oxidation of Reactive
Dyes in Simulated Dyehouse Effluents by Ferrioxalate-Fenton/UV-A and TiO2/UV-A Processes, Dyes and
Pigments, 47, 207-218.
7. Arslan Alaton, I., Akmehmet Balcioglu, I. and Bahnemann, D.W. (2002) Advanced Oxidation of a Reactive
Dyebath Effluent: Comparison of O3,H2O2/UV-C and TiO2/UV-A Processes, Water Research, 36, 1143-
1154.
8. Arslan-Alaton, I. and Alaton, I. (2007) Degradation of Xenobiotics Originating from the Textile Preparation,
Dyeing, and Finishing Industry Using Ozonation and Advanced Oxidation. Ecotoxicology and
Environmental Safety, 68, 98-107.
9. Azbar, N., Yonar, T. and Kestioglu, K. (2004) Comparison of Various Advanced Oxidation Processes and
Chemical Treatment Methods for COD and Color Removal from a Polyester and Acetate Fiber Dyeing
Effluent. Chemosphere, 55, 35-43.
10. Bali, U., Catalkaya, E. and Sengul, F. (2004) Photodegradation of Reactive Black 5, Direct Red 28 and
Direct Yellow 12 Using UV, UV/H2O2 and UV/H2O2/Fe+2: A Comparative Study, Journal of Hazardous
Materials B, 114, 159-166.
11. Beltran, F. J., Rivas, F. J. and Gimeno, O. (2005) Comparison Between Photocatalytic Ozonation and Other
Oxidation Processes for the Removal of Phenols from Water, J Chem Technol Biotechnol, 80, 973-984.
12. Benitez, E. J., Beltran-Heredia, J., Acero, R. L. and Gonzalez, T. (1996) Degradation of Protocatechuic Acid
by Two Advanced Oxidation Processes: Ozone/UV Radiation and H2O2/UV Radiation, Water Res., 30, 1597-
1604.
13. Bolton, J. R. (2001) Ultraviolet Applications Handbook, Bolton Photosciences Inc., Edmonton, Canada, p.
40.
14. Chiron S., Fernandez-Alba, A., Rodriguez, A. and Calvo, E. G. (2000) Pesticide Chemical Oxidation: Stateof-
the-Art, Water Research, 34(2), 366-377.
15. Crittenden, J. C., Hu, S., Hand, D.W. and Gren, S. A. (1999) A Kinetic Model for H2O2/UV Process in a
Completely Mixed Batch Reactor, Water Research, 33, 2315-2328.
16. Çokay Çatalkaya, E. and Kargı, F. (2007) Advanced Oxidation Treatment of Pulp Mill Effluent for TOC and
Toxicity Removals, Journal of Environmental Management, 87, 396-404.
17. Domenech, X., Jardim, W. F. and Litter, M. (2001) Elimination of Pollutants by Heterogeneous
Photocatalysis[M]. Latin-American Cooperation CYTED. Science and Technology for the Development,
Buenos Aires, Argentina, Chapter 1, 15 p.
18. Eremektar, G., Selcuk, H. and Meric, S. (2007) Investigation of the Relation Between COD Fractions and the
Toxicity in a Textile Finishing Industry Wastewater: Effect of preozonation, Desalination, 211, 314-320.
19. Feng X., Zhu, S. and Hou, H. (2006) Investigation of 207 nm UV Radiation for Degradation of Organic Dye
in Water, Water SA, 32(1), 43-48.
20. Garcia, J. C., Oliveira, J. L., Silva, A. E. C., Oliveira, C. C., Nozaki, J. and de Souza, N. E. (2007)
Comparative Study of the Degradation of Real Textile Effluents by Photocatalytic Reactions Involving
UV/TiO2/H2O2 and UV/Fe+2/H2O2 Systems, Journal of Hazardous Materials, 147, 105-110.21. Glaze, W. H. (1987) Drinking-Water Treatment with Ozone, Environ. Sci. Technol., 21, 224-230.
22. Gogate, P. R. and Pandit, A. B. (2004a) A Rewiev of Imperative Technologies for Wastewater Treatment I:
Oxidation Technologies at Ambient Conditions, Advances in Environmental Research, 8, 501-551.
23. Gogate, P. R. and Pandit, A. B. (2004b) A Review of Imperative Technologies for Wastewater Treatment II:
Hybrid Methods, Advances in Environmental Research, 8, 553-597.
24. Gonzalez, M. G., Oliveros, E., Worner, M. and Braun, A. M. (1994) Vacuum-Ultraviolet Photolysis of
Aqueous Reaction Systems, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 5,
225-246.
25. Han, W., Zhu, W., Zhang, P., Zhang, Y. and Li, L. (2004) Photocatalytic Degradation of Phenols in Aqueous
Solution Under Irradiation of 254 and 185 nm UV Light, Catalysis Today, 90, 319-324.
26. Huang, C. P., Dong, Ch. and Tang, Z. (1993) Advanced Chemical Oxidation: Its Present Role and Potential
Future in Hazardous Waste Treatment, Waste Management, 13, 361-377.
27. Huang, X. and Wang, X. M. (2007) Toxicity Change Patterns and its Mechanism During the Degradation of
Nitrogen-Heterocyclic Compounds by O3/UV, Chemosphere, 69, 747-754.
28. Kestioğlu K., Yonar, T. and Azbar, N. (2004) Feasibility of Physico-Chemical Treatment and Advanced
Oxidation Processes (AOPs) as a Means of Pretreatment of Olive Mill Effluent (OME), Chemosphere, 55,
35-43.
29. Kestioğlu, K. ve Yalılı, M. (2006). Yüksek KOİ İçerikli Tekstil Atıksularının Kimyasal Çökeltim ve
Adsorpsiyon Yöntemleriyle Arıtılabilirliği, Ekoloji, 15(59), 27-31.
30. Legrini, O., Oliveros, E. and Braun, A. M. (1993) Photochemical Processes for Water Treatment, Chem.
Rev., 93, 671-698.
31. Lens, P., Pol, L. H., Wilderer, P. and Asano, T. (2002) Water Recycling and Resource Recovery in Industry,
IWA Publishing, London, UK.
32. Loraine, G.A. and W.H. Glaze, (1992) Destruction of Vapour Phase Halogenated Methanes by Means of
Ultraviolet Photolysis, 47th Purdue Industrial Waste Conference Proceedings, Lewis Publishers, Inc.
Chelsea, Michigan, 367-376, USA.
33. Metcalf&Eddy (1991). Wastewater Engineering: Treatment, Disposal and Reuse, McGraw-Hill, Inc., New
York.
34. Mokrini, A., Ousse, D. and Esplugas, S. (1997) Oxidation of Aromatic Compounds with UV
Radiation/Ozone/Hydrogen Peroxide, Wat. Sci. Tech., 35(4), 95-102.
35. Muruganandham, M. and Swaminathan, M. (2006) Advanced Oxidative Decolourisation of Reactive Yellow
14 Azo Dye by UV/TiO2, UV/H2O2, UV/H2O2/Fe+2 Processes-A Comparative Study, Separation and
Purification Technology, 48, 297-303.
36. Muruganandham, M., Selvam, K. and Swaminathan, M. (2007) A Comparative Study of Quantum Yield and
Electrical Energy per Order (Eeo) for Advanced Oxidative Decolourisation of Reactive Azo Dyes by UV
Light, Journal of Hazardous Materials, 144, 316-322.
37. Muthukumar M. and N. Selvakuma (2004) Studies on the Effect of Inorganic Salts on Decolouration of Acid
Dye Effluents by Ozonation, Dyes and Pigments, 62, 221-228.
38. Park, J.H., Cho, I.H. and Chang, S.W. (2006) Comparison of Fenton and Photo-Fenton Processes for
Livestock Wastewater Treatment, Journal of Environmental Science and Health Part B, 41, 109-120.
39. Peyton, G. R. and Glaze, W. H. (1982) Destruction of Pollutants in Water with Ozone in Combination with
Ultraviolet Radiation. 2. Natural Trihalomethane Precursors, Environ. Sci. Technol., 16, 454-458.
40. Peyton, G. R. and Glaze, W. H. (1988) Destruction of Pollutants in Water with Ozone in Combination with
Ultraviolet Radiation. 3. Photolysis of Aqueous Ozone, Environ. Sci. Technol., 22, 761-767.
41. Sarayu K., Swaminathan, K. and Sandhya, S. (2007) Assessment of Degradation of Eight Commercial
Reactive Azo Dyes Individually and in Mixture in Aqueous Solution by Ozonation, Dyes and Pigments, 75,
362-368.
42. Sanchez-Polo, M., Rivera-Utrilla, J., Mendez-Diaz, J. D., Canonica, S. and von Gunten, U. (2007)
Photooxidation of Naphthalenesulfonic Acids: Comparison Between Processes Based on O3, O3/Activated
Carbon and UV/H2O2, Chemosphere, 68, 1814-1820.
43. Sauer, T.P., Casaril, K., Oberziner, A.L.B., Jose, H.J. and Moreira, R.F.P.M. (2006) Advanced Oxidation
Processes Applied to Tannery Wastewater Containing Direct Black 38—Elimination and Degradation
Kinetics, Journal of Hazardous Materials, B135, 274-279.44. Sevimli, M. F. ve Sarıkaya, H. Z. (2002) Ozone Treatment of Textile Effluents and Dyes: Effect of Applied
Ozone Dose, pH and Dye Concentration, Journal of Chemistry and Biotechnology, 77, 842-850.
45. Song, Z., Williams, C. J. and Edyvean, R. G. J. (2004) Treatment of Tannery Wastewater by Chemical
Coagulation, Desalination, 164, 249-259.
46. Uddin A. B. M, Amat Ngilmi, A. S. and Mohd Asri, M. N. (2003). Effectiveness of Peat Coagulant for the
Removal of Textile Dyes from Aqueous Solution and Textile Wastewater, Malaysian Journal of Chemistry,
5(1), 34 -43.
47. Wu, J.J., Muruganandham, M. and Chen, S. H. (2007) Degradation of DMSO by Ozone-Based Advanced
Oxidation Processes, Journal of Hazardous Materials, 149, 218-225.
48. Yasar, A., Ahmad, N. and Khan, A. A. A. (2006) Energy Requirement of Ultraviolet and AOPs for the Post-
Treatment of Treated Combined Industrial Effluent, Coloration Technology, 122, 201-206.
49. Yonar, T. (2005a) Fotokimyasal Oksidasyon Yöntemiyle Organik Kirliliklerin Giderilmesi ve Bu Yöntemin
Küçük Yerleşim Bölgelerinden Kaynaklanan Atıksulara Uygulanması, Uludağ Üniversitesi Fen Bilimleri
Enstitüsü, Yayınlanmamış Doktora Tezi, Bursa, 194 s.
50. Yonar, T., Kaplan Yonar, G., Kestioğlu, K. ve Azbar, N. (2005b) Decolorisation of Textile Effluent Using
Homogeneous Photochemical Oxidation Processes, Coloration Technology, 121, 258-264.
51. Zayas, P. T., Geissler, G. and Hernandez, F. (2007) Chemical Oxygen Demand Reduction in Coffee
Wastewater Through Chemical Flocculation and Advanced Oxidation Processes, Journal of Environmental
Sciences, 19, 300-305.
52. Zhou, H. and Smith, D. W. (2002) Advanced Technologies in Water and Wastewater Treatment, J. Environ.
Eng. Sci., 1, 247-264.

Thank you for copying data from http://www.arastirmax.com