You are here

MTBE’NİN ÇEVRESEL ETKİLERİ VE GİDERİMİNE YÖNELİK ARITMA TEKNİKLERİ

Environmental Effects and Treatment Methods of MTBE

Journal Name:

Publication Year:

Abstract (2. Language): 
In this study the gasoline additive methyl tert-butyl ether (MTBE)’s environmental effects because of leaking and spilling from underground storage tanks were determined and several methods are currently used to remove MTBE from MTBE-contaminated groundwaters were rewiewed. In this well rounded literature study, the importance of MTBE removal for environmental health has been emphasized and the reason why AOP’s are commonly preferred as well as conventional treatment methods in the refining of waters polluted with MTBE has been indicated. Currently used treatment methods were classified and suggestions about solving the existing problems were evaluated.
Abstract (Original Language): 
Bu çalışmada, yakıt katkı maddesi olarak kullanılan metil tersiyer bütil eter (MTBE)’in yeraltı depolama tanklarından sızması ve dökülmesi ile yüzey ve yeraltı suyu kaynaklarına karışması neticesinde oluşturacağı çevresel etkiler tanımlanmış ve MTBE’nin su ortamından giderimine yönelik günümüzde uygunlanabilecek arıtma teknikleri değerlendirilmiştir. Geniş kapsamlı bir literatür çalışması şeklinde hazırlanmış bu makalede, toksik organik bir bileşik olan MTBE gideriminin çevre sağlığı yönünden önemi vurgulanmış ve MTBE ile kirlenmiş suların arıtılmasında geleneksel arıtma teknikleri yanında özellikle İOP’nin yaygın olarak tercih edilmesinin nedenleri belirtilmiştir. MTBE’nin gideriminde kullanılabilecek arıtma tekniklerinin özellikleri ve bu tekniklerin karşılaştırılması yapılarak bazı çözüm önerileri verilmiştir.
169-181

REFERENCES

References: 

1. Ahmed, F.E. (2001) Toxicology and human health effects following exposure to oxygenated or reformulated
gasoline, Toxicology Letters, 123; 89–113.
2. Akbal F., Balkaya N. (2002) Toksik Organik Kirleticilerin Gideriminde İleri Oksidasyon Teknolojileri,
YTÜD, 2002/4, 47-55
3. Anonim (2002) Drinking Water and MTBE: A Guide for Private Well Owners (Brochure). Board of Regents
of the University of Wisconsin System.
4. Anonim (2009) en.wikipedia.org
5. Baehr, A.L., Stackelberg, P.E., Baker, R.J. (1999) Evaluation of the atmosphere as a source of volatile organic
compounds in shallow groundwater: Water Resources Research, v. 35, no. 1, p. 127–136.
6. Bahnemann D., Bockelman, D., Goslich, R. (1991) Mechanistic Studies of Water Detoxification inminated
TiO2 Suspensions, Solar Energy Materials, 24, 564-583, 1991
7. Baker, R.J., Best, E.W., and Baehr, A.L. (2002) Used motor oil as a source of MTBE, TAME, and BTEX to
ground water: Ground Water Monitoring & Remediation, v. 22, no. 4, p. 46–51.
8. Baus C, Hung H-W, Sacher F, Fleig M, Brauch H-J. (2005) MTBE in drinking water production - occurrence
and efficiency of treatment technologies. Acta Hydrochimica et Hydrobiologica ,33(2):118-132.9. Baus C. Sona M. Brauch H. (2007) Ozonation and combined ozone/H2O2, UV/ozone and UV/H2O2 for treatment
of fuel oxygenates MTBE, ETBE, TAME, and DIPE from water – a comparison of removal efficiencies
Water Science & Technology 55 (12): 307–311
10. Belpoggi, F., Soffriti, M., Marltoni, C. (1998) Pathological characterization of testicular tumors and lymphomas-
leukemias, and their precursors observed in Sprague-Dawley rats exposed to methyl tertiary-butyl ether
(MTBE). European Journal of Oncology 3 (3), 201-206.
11. Bengtsson, B.E., Tarkpea, M. (1983) The acute aquatic toxicity of some substances carried by ships. Marine
Pollution Bulletin 14 (6), 213-214.
12. Birgül A., Solmaz S.K.A. (2007) Tekstil Endüstrisi Atıksuları Üzerinde İleri Oksidasyon ve Kimyasal Arıtma
Prosesleri Kullanılarak KOI ve Renk Gideriminin Araştırılması Ekoloji 15, 62, 72-80
13. Burbano A., Dionysiou D., Suidan M., Richardson T. (2005) Oxidation kinetics and effect of pH on the degradation
of MTBE with Fenton reagent Water Research 39, 107–118
14. Cater S., Stefan M., Bolton J., Safarzadeh-Amiri A. (2000) UV/H2O2 Treatment of Methyl tert-Butyl Ether in
Contaminated Waters 34 (4) : 659–662
15. Chan, M.S., Lynch R.J. (2003) Photocatalytic degradation of aqueous methyl-tert-butyl ether (MTBE) in a
supported-catalyst reactor, Environ Chem Lett.,1:157–160
16. Çokay E., Şengül F. (2006) Toksik Kirleticilerin İleri Oksidasyon Prosesleri İle Arıtımı DEÜ Mühendislik
Fakültesi Fen ve Mühendislik Dergisi 8: 2 ,1-9
17. Dakhel, N., Pasteris, G., Werner, D., and Höhener, P. (2003) Small-volume releases of gasoline in the vadose
zone—Impact of the additives MTBE and ethanol on groundwater quality: Environmental Science & Technology,
v. 37, no. 10, p. 2127–2133.
18. Deeb, R. A., Chu, K.-H., Shih, T., Linder, S., Suffet, I., Kavanaugh, M. C., Alvarez-Cohen, L. (2003) MTBE
and other oxygenates: environmental sources, analysis, occurrence, and treatment. Environ.Eng. Sci., 20 (5),
433-447.
19. Dourson, M.L., Felter, S.P. (1997) Route-to-route extrapolation of the toxic potency of MTBE. Risk Anal.
17, 717–725.
20. Drottar, K.R., Mank, M.A., Palmer, S.J., Sulaiman, M.W., Springer, T.S., Krueger, H.O. (1998) Toxicity of
methyl tertiary-butyl ether (MTBE) to selected marine and freshwater organisms. Abstract, SETAC 19th Annual
SETAC Meeting, 15-19 November 1998, Charlotte, NC, USA.
21. EPA (Environmental Protection Agency) (1999) Achieving Clean Air and Clean Water. The Report of the
Blue Ribbon Panel on Oxygenates in Gasoline. US EPA 420-R-99-021. Washington, DC.
22. Garoma T., Gurol M.D. (2006) Oxidation of Methyl Tert-Butyl Ether in Aqueous Solution by an Ozone/UV
Process Journal of Environmental Engineering, 132:11, 1404-1412
23. Garoma T., Gurol M.D. (2008) Comprehensive Kinetic Model for the Degradation of Methyl tert-Butyl Ether
by an Ozone/UV Process Ind. Eng. Chem. Res., 47 (20), 7654–7662
24. Graham, J. L., Striebich, R., Patterson, C. L., Radha Krishnan, E., Haught, R. C. (2004) MTBE oxidation by
products from the treatment of surface waters by ozonation an UV-Ozonation. Chemosphere., 54: 1011-1016
25. Hockett, J.R. (1997a). Acute Toxicity of MTBE to Daphnia magna Under Static-renewal Test Conditions
(Study Number 0480-378-003-001). ENSR, Fort Collins, CO, USA.
26. Hockett, J.R. (1997b) Short-term Sub-chronic Toxicity of MTBE to Ceriodaphnia dubia Under Staticrenewal
Test Conditions (Study Number 0480-378-004-001). ENSR, Fort Collins, CO, USA.
27. HSDB (1997) Hazardous Substances Data Bank (HSDB): t-Butyl Methyl Ether. Last revised on April 23,
1997. Bethesda, Maryland: National Library of Medicine (NLM), National Toxicology Program (NTP).
28. Hu, Q., Zhang, C., Wang, Z., Chen, Y., Mao, K., Zhang, X., Xiong, Y., Zhu, M. (2007) Photodegradation of
methyl tert-butyl ether (MTBE) by UV/H2O2 and UV/TiO2, Journal of Hazardous Material, 154(1-3):795-
803
29. Kang J., ve Hoffmann M., (1998) Kinetics and Mechanism of the Sonolytic Destruction of Methyl tert-Butyl
Ether by Ultrasonic Irradiation in the Presence of Ozone Environ. Sci. Technol., 32 (20), 3194–3199
30. Keller AA, Sandall OC, Rinker RG, Mitani MM, Bierwagen B, Snodgrass MJ. (2000) An evaluation of physicochemical
treatment technologies for water contaminated with MTBE. Ground Water Monitor Remed
20:114–134
31. Keller, A.A., Froines J., Koshland C., Reuter J., Suffet I., Last J. (1998a) Health & Environmental Assessment
of MTBE, Summary and Recommendations, in Health and environmental assessment of MTBE, vol. 1.
UC Toxics Research and Teaching Program, UC. Davis.32. Keller, A.A., Sirivithayapakorn, S., Kram, M. (1999) Remediation of MTBE contaminated water and soil.
Remed J 10:55–68
33. Keller, AA, Sandall, OC, Rinker, RG, Mitani, MM, Bierwagen, B and Snodgrass, MJ. (1998b) Cost and
Performance Evaluation of Treatment Technologies for MTBE-Contaminated Water. UC SR&TP Report to
the Governor of California
34. Kinner N.E. (2001) Fate, transport ve remediation of MTBE. Bedrock: Bioremediation Center / Environmental
Engineering University of New Hampshire Durham, NH. April 23. avaliable at:
http://www.asce.org/pdf/kinnertestimony
35. Klauson D., Portjanskaja E. , Preis S. (2008) Visible light-assisted photocatalytic oxidation of organic pollutants
using nitrogen-doped titania Environ Chem Lett 6:35–39
36. Kuburovic, N., Todorovic, M., Raicevic, V., Orlovic, A., Jovanovic, L., Nikolic, J., Kuburovic, V., Drmanic,
S., Solevic, T. (2007) Removal of methyl tert-butyl ether from wastewaters using photolytic, photocatalytic
and microbiological degradation processes. Desalination, 213, 123-128.
37. Lane J., Eighmey C., Timmons T., Pate D. (2002) Technologies for Treating MTBE and Other Fuel Oxygenates
Unıversıty of Mıssourı - Rolla Final Report Comparatıve Treatment Study Of MTBE and Alternatıve
Fuel Oxygenates
38. Lia K., Hokanson D., Crittenden J., Trussell R., Minakata D. (2008) Evaluating UV/H2O2 Processes For
Methyl Tert-Butyl Ether And Tertiary Butyl Alcohol Removal: Effect Of Pretreatment Optionsand Light Sources
Water Research 42 : 5045 – 5053
39. Longo, S.E. (1995) Effects of Methyl tert-butyl Ether and Naphthalene on the Embryo of the Japanese Medaka
(Oryzias latipes). MS thesis, Graduate School-New Brunswick Rutgers, The State University of New
Jersey and The Graduate School of Biomedical Sciences Robert Wood Johnson Medical School, NJ, USA.
40. Malley, J.P.,Eliason P.A, Wagler J.L. (1993) Point-of-entry treatment of petroleum contaminated ground
water. Water Environment Research 65(2): 119-128.
41. Naddafi, K., Nabizadeh, R., Baiggi A. (2008) Bioassay of methyl tertiary-butyl ether (MTBE) toxicity on
rainbow trout fish, Journal of Hazardous Materials 154; 403–406
42. Pasteris, G., Werner, D., Kaufmann, K., Höhener, P., (2002) Vapor phase transport and biodegradation of
volatile fuel compounds—A large scale lysimeter experiment: Environmental Science & Technology, v. 36,
no. 1, p. 30–39.
43. Peter A., Von Gunten U.(2007) Oxidation Kinetics of Selected Taste and Odor Compounds During Ozonation
of Drinking Water Environ. Sci. Technol., 41 (2), 626–631
44. Richardson D. (2003) Water Analysis: Emerging Contaminants and Current Issues Anal. Chem., 75 (12),
2831–2857
45. Robert, D., Malato, S. (2002) Solar photocatalysis: a clean process for water detoxification. Sci. Total Environ.,
291, 85-97.
46. Rosal R., Rodriguez A., Perdigon-Melon J., Petre A.,Garcia-Carva E. (2008) Oxidation of dissolved organic
matter in the effluent of a sewage treatment plant using ozone combined with hydrogen peroxide (O3/H2O2)
Chemical Engineering Journal doi:10.1016/j.cej.2008.11.019
47. Safarzadeh-Amiri, A. (2001) O3/H2O2 Treatment Of Methyl-Tert-Butyl Ether(MTBE) In Contaminated
Waters Wat. Res. 35: 15, 3706–3714
48. Sahle-Demessie, E., Enriquez J., Gupta, E.G. (2002) Attenuation of methyl tert-butyl ether in water using
sunlight and a photocatalyst: Water Environment Research, v. 74, no. 2, p. 122-130.
49. Salari D., Daneshvar N., Aghazadeh F., Khataee A.R. (2005) Application of artificial neural networks for
modeling of the treatment of wastewater contaminated with methyl tert-butyl ether (MTBE) by UV/H2O2
process, Journal of Hazardous Materials 125: 205–21
50. Selli E., Bianchi C.L., Pirola C. Bertelli M. (2004) Degradation of methyl tert-butyl ether in water: effects of
the combined use of sonolysis and photocatalysis Ultrasonics Sonochemistry 12: 395–400
51. Siedlecka E.M, Stepnowski P. (2006) Decomposition rates of methyl tert-butyl ether and its by-products by
the Fenton system in saline wastewaters Separation and Purification Technology 52 : 317–324
52. Siedlecka E.M, Stepnowski P. (2007). Application of fenton and fenton-like process for the oxidation of
MTBE and its by-products in saline wastewaters. September. Faculty of Chemistry, University of Gdansk, ul.
Sobiesko 18, PL-80-952 Gdansk, Poland.
53. Siedlecka E.M, Wiechowska A., Stepnowski P. (2007) Influence of inorganic ions on MTBE degradation by
Fenton’s reagent Journal of Hazardous Materials 147 :497–50254. Solmaz S.K.A., Üstün G.E., Birgül A., Yonar T. (2009) Advanced Oxidation Of Textile Dyeıng Effluents:
Comparison Of Fe+2/H2O2, Fe+3/H2O2, O3 And Chemical Coagulation Processes (Basım aşamasındadır)
55. Squillace P.J, Pankow J.F, Korte N.E, Zogorski J.S. (1997) Review of the environmental behavior and fate of
methyl tert-butyl ether (MTBE). J. Environ. Toxicol. Chemistry 16(9): 1836-1844. September.
56. Sutherland,J., Adams C., Kekobad J. (2004) Treatment of MTBE by air stripping, carbon adsorption, and
advanced oxidation: technical and economic comparison for five groundwaters, Water Research 38:193–205
57. U.S. EPA (1997) Drinking Water Advisory: Consumer Acceptability Advice and Health Effects Analysis on
Methyl Tertiary-Butyl Ether (MTBE). December. Fact Sheet 4 pp. And Advisory 42 pp. EPA-822-F-97-009.
ODW 4304. Health and Ecological Criteria Division, Office of Science and Technology, Office of Water,
U.S. Environmental Protection Agency. Washington, D.C.: U.S. EPA.
58. Üstün G.E., Solmaz S.K.A., Birgül A. (2007) Regeneration of industrial district wastewater using a combination
of fenton process and ion exchange-A case study” , Resources, Conservation and Recycling,52(2),425-
440
59. Wang, Y., Chen, C., Wu T., Xu J., Han, X. (2008) Methyl tert-butyl ether (MTBE) induced Ca2+-dependent
cytotoxicity in isolated rabbit tracheal epithelial cells, Toxicology in Vitro 22 ; 1734–1741
60. Werner, I., Kogera, C.S., Deanovic, L.A., Hinton, D.E. (2001) Toxicity of methyl-tert-butyl ether to
freshwater organisms, Environmental Pollution 111 83-88
61. Wilhelm, M.J., Adams,V.D, Curtis J.G, Middlebrooks E.J (2002) Carbon Adsorption and Air-Stripping
Removal of MTBE from River Water J. Envir. Eng.128: 813-823
62. Zang Y., Farnood R., (2005) Photocatalytic decomposition of methyl tert-butyl ether in aqueous slurry of
titanium dioxide Applied Catalysis B: Environmental Volume 57, Issue 4, 26 May 2005, Pages 275-282
63. Zogorski JS, Morduchowitz A, Baehr AL, Bauman BJ, Drew RT, Korte NE,Lepham WW, Pankow JF, &
Washington ER. (1996) Fuel oxygenates and water quality: Current understanding of sources, occurrence in
natural waters, environmental behavior, fate, and significance. Washington, DC, Office of Science and Technology
Policy, 91 pp (Final report prepared for the Interagency Oxygenated Fuel Assessment).
64. Zogorski, J. S., Carter, J. M., Ivahnenko, T., Lapham, W.W., Moran, M.J., Rowe, B.L., Squillace, P.J., and
Toccalino, P.L. (2006) The quality of our Nation’s waters -Volatile organic compounds in the Nation’s ground
water and drinking-water supply wells. U.S. Geological Survey Circular 1292.

Thank you for copying data from http://www.arastirmax.com