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Perhidrobenzimidazolyum Tuzlarının Suzuki-Miyaura Eşleşme Tepkimelerindeki Katalitik Aktivitesi

Catalytic Activity of Perhydrobenzimidazolium Salts in Suzuki-Miyaura Coupling Reactions

Journal Name:

  • Adıyaman University Journal of Science

Publication Year:

  • 2014

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
1,3-Dialkylperhydrobenzimidazolium chloride salts as N-heterocyclic carbene precursors were synthesised by reaction of secondary amines with ammonium chloride in triethyl orthoformate at 130 ºC. Prepared salts were used as catalyst for coupling reactions of phenylboronic acid with aryl halides and substituted biaryl compounds were obtained in high yields.
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Abstract (Original Language): 
N-Heterosiklik karben öncülleri olan 1,3-dialkilperhidrobenzimidazolyum klorür tuzları, sekonder aminlerin amonyum klorür ile trietil ortoformat içersinde 130 ºC’de ısıtılmaları sonucu sentezlendi. Hazırlanan tuzlar fenilboronik asit ile aril halojenlerin eşleşme reaksiyonlarında katalizör olarak kullanıldı ve yüksek verimlerle sübstitüye biaril bileşikleri elde edildi.
FULL TEXT (PDF): 
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  • Turkish

REFERENCES

References: 

[1] S. Kaye, J. M. Fox, F. A. Hicks, S. L. Buchwald, Adv. Synth. Catal., 2001, 343, 789.
[2] M. Kertesz, C. H. Choi, S. Yang, Chem. Rev., 2005, 105, 3448.
[3] S. Kotha, K. Lahiri, D. Kashinath, Tetrahedron, 2002, 58, 9633.
[4] S. Lightowler, M. Hird, Chem. Mater., 2005, 17, 5538.
[5] N. Miyaura, T. Yanagi, A. Suzuki, Synth. Commun., 1981, 11, 513.
[6] M. Gruber, S. Chouzier, K. Koehler, L. Djakovitch, Appl. Catal. A: Gen. 2004, 265, 161.
[7] L. Bai, J. Xian, Y. Zhang, Green Chem., 2003, 5, 615.
[8] C. G. Blettner, W. A. König, W. Stenzel, T. Schotten, J. Org. Chem., 1999, 64, 3885.
[9] F. Chanthavong, N. E. Leadbeater, Tetrahedron Lett., 2006, 47, 1909.
[10] R. K. Arvela, N. E. Leadbeater, T. L. Mack, C. M. Kormos, Tetrahedron Lett., 2666, 47,
217.
[11] A. F. Littke, G. C. Fu, J. Am. Chem. Soc., 2001, 123, 6989.
[12] W. A. Herrmann, V. P. W. Böhm, C. P. Reisinger, J. Organomet. Chem., 1999, 576, 23.
[13] K. M. Wu, C. A. Huang, K. F. Peng, and C. T. Chen, Tetrahedron, 2005, 61, 9679.
[14] Y. C. Lai, H. Y.Chen, W. C. Hung, C. C. Lin, F. E. Hong, Tetrahedron, 2005, 61, 9484.
[15] B. Tao, D. W. Boykin, Tetrahedron Lett., 2003, 44, 7993.
17
[16] P. A. Gossage, H. A. Jenkins, P. N. Yadav, Tetrahedron Lett., 2004, 45, 7689.
[17] M. R. Buncmeiser, K. Wurst, J. Am. Chem. Soc., 1999, 121, 11101.
[18] S. Iyer, G. M. Kulkarni, C. Ramesh, Tetrahedron, 2004, 60, 2163.
[19] T. Mino, Y. Shirae, M. Sakamoto, T. Fujita, J. Org. Chem., 2005, 70, 2191.
[20] X. Cui, Y. Zhou, N. Wang, L. Liu, Q. X. Guo, Tetrahedron Lett., 2007, 48, 163.
[21] E. Çetinkaya, P.B. Hitchcock, H. A. Jasim, M. F. Lappert, K. J. Spyropoulos, Perkin Trans., 1992, 1, 561.
[22] S. Saba, A. Brescia, M. K. Kaloustian, Tetrahedron Lett., 1991, 32, 5031.
[23] A. J. Arduengo III, R. Krafczyk, R. Schmutzler, Tetrahedron, 1999, 55, 14523.
[24] İ. Özdemir, S. Demir, S. Yaşar, B. Çetinkaya, Appl. Organometal. Chem., 2005, 19, 55.
[25] İ. Özdemir, Y. Gök, N. Gürbüz, E. Çetinkaya, B. Çetinkaya, Heteroatom Chem., 2004,
15, 419.
[26] İ. Özdemir, Y. Gök, N. Gürbüz, B. Çetinkaya, Turk. J. Chem., 2007, 31, 397.
[27] M. Yiğit, Molecules, 2009, 14, 2032.
[28] B. Yiğit, M. Yiğit, İ. Özdemir, E. Çetinkaya, Turk. J. Chem., 2010, 34, 327.
[29] B. Yiğit, M. Yiğit, İ. Özdemir, E. Çetinkaya, Heterocycles, 2010, 81, 943.
[30] M. Yiğit, G. Bayam, B. Yiğit, İ. Özdemir, Heterocycles, 2013, 87, 897.

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