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(2,3-Difenil-1,3-oksazolidin-5-il)metil Metakrilat’ın Metil Metakrilat ile Kopolimerlerinin Sentezi, Karakterizasyonu ve Termal Özellikleri

Copolymers of (2,3-Diphenyl-1,3-oxazolidin-5-yl)methyl Methacrylate with Methyl Methacrylate: Synthesis, Characterization and Thermal Properties

Journal Name:

  • Adıyaman University Journal of Science

Publication Year:

  • 2012

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
In this work, (2,3-diphenyl-1,3-oxazolidin-5-yl)methyl methacrylate(DOMMA) was synthesized by condensation reaction of N-benzyliden aniline with glycidyl methacrylate (GMA) in the presence of SnCl 4 as catalyst. Homopolymerization and copolymerization of this monomer with methyl methacrylate were carried out by free radical polymerization in dioxane solution using α-α'-Azobisisobutyronitrile (AIBN) as initiator at 70 o C. FT-IR, 1 H-NMR and 13 C-NMR techniques were used in characterization of the monomer, homopolymer and copolymers. The glass transition temperature and thermal stabilities of the homopolymer and the copolymers were investigated by DSC and TGA, respectivelly. The molecular weight of the homopolymer was determined by GPC
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Abstract (Original Language): 
Bu çalışmada (2,3-difenil-1,3-oksazolidin-5-il)metil metakrilat (DOMMA), glisidil metakrilat (GMA) ile N-benziliden anilinin SnCl 4 katalizörü yanında kondenzasyon reaksiyonu ile sentezlendi. Bu monomerin homopolimerizasyonu ve metil metakrilat monomeri ile kopolimerizasyonu, α-α'-Azobisizobütironitril (AIBN) başlatıcısı varlığında dioksan çözeltisinde 70 o C’de serbest radikalik yolla gerçekleştirildi. Monomer, homopolimer ve kopolimerlerin karakterizasyonunda FT-IR, 1 H-NMR ve 13 C-NMR teknikleri kullanıldı. Homopolimer ve kopolimerlerin camsı geçiş sıcaklıkları DSC, termal kararlılıkları TGA ile araştırıldı. Homopolimerin molekül ağırlığı GPC ile belirlendi.
FULL TEXT (PDF): 
PDF icon arastirmax-23-difenil-13-oksazolidin-5-ilmetil-metakrilatin-metil-metakrilat-ile-kopolimerlerinin-sentezi-karakterizasyonu-termal-ozellikleri.pdf
  • 2
75-85
  • Turkish

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