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MOBİLYA ENDÜSTRİSİ ATIKLARINDAN KATALİTİK PİROLİZ YÖNTEMİ İLE BİYOYAKIT ÜRETİMİ

BIO-OIL PRODUCTION FROM CATALYTIC PYROLYSIS METHOD OF FURNITURE INDUSTRY SAWDUST

Journal Name:

  • Gazi Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi

Publication Year:

  • 2013

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
In this study, scots pine (Pinus sylvestris L.) sawdust was used as biomass resources. Catalyzed and uncatalyzed (thermal) pyrolysis processes were conducted in a fixed-bed reactor. The effects of the parameters on pyrolysis product yields such as temperature and catalysis type were investigated. The pyrolysis of the experimental samples that have a particle size in the range of 0.850-1.60 mm were carried out at the temperatures of 400, 500 and 600 °C at the heating rate of 5°C/min. Nitrogen gas (N2) flow was used at the rate of 30 ml/min during the process. Basic salts such as Na2CO3, K2CO3 and Lewis acid (FeCl3) were used as catalyses. As a result, it was determined that temperature and catalysis types were effective parameters in the yields of char, bio-oil and gas products. Also it was determined that the conversion of wood materials into fuel or valuable chemicals with the pyrolysis method is an applicable technology.
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Abstract (Original Language): 
Bu çalışmada, sarıçam (Pinus sylvestris L.) odun talaşı biyokütle kaynağı olarak değerlendirilmiş, sabit yataklı reaktörde, katalizörlü ve katalizörsüz (termal) pirolizi gerçekleştirilmiştir. Deneylerde piroliz ürünlerinin verimleri üzerine sıcaklık ve katalizör tipi gibi parametrelerin etkisi araştırılmıştır. 0,850-1,60 mm parçacık boyutundaki deney örneklerinin pirolizi; 400, 500 ve 600 °C sıcaklıklarda, 5 °C/min ısıtma hızında ve 30 ml/min sürükleyici azot gazı (N2) akış hızında gerçekleştirilmiştir. Katalizör olarak Na2CO3 ve K2CO3 bazik tuzları ile FeCl3 Lewis asidi kullanılmıştır. Sonuç olarak, sıcaklık ve katalizör tipinin katı, sıvı ve gaz ürün verimlerinde etkili parametreler olduğu belirlenmiştir. Ayrıca odun talaşlarından katalitik piroliz yöntemi ile elde edilen sıvı ürünlerin biyoyakıt veya değerli kimyasal madde olarak kullanılabileceği tespit edilmiştir.
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REFERENCES

References: 

1. Calkins, M., “Materials for sustainable sites”, John
Wiley & Sons Inc., Hoboken, New Jersey, 14-24,
2009.
2. Inderwildi, O. R. and King, D. A., “Quo vadis
biofuels?”, Energy & Environmental Science, 2
(4): 343-346 ,2009.
3. Kantarelis, E. and Zabaniotou, A., “Valorization of
cotton stalks by fast pyrolysis and fixed bed air
gasification for syngas production as precursor of
second generation biofuels and sustainable
agriculture”, Bioresource Technology, 100 (2):
942-947, 2009.
4. Qi, W. Y, Hu, C. W., Li, G. Y., Guo, L. H., Yang,
Y., Luo, J., Miao, X. and Du, Y., “Catalytic
pyrolysis of several kinds of bamboos over zeolite
NaY”, Green Chemistry, 8 (2): 183-190, 2006.
5. Wang, C., Du, Z., Pan, J., Li, J. and Yang, Z.,
“Direct conversion of biomass to bio-petroleum at
low temperature”, Journal of Analytical and
Applied Pyrolysis, 78 (2): 438-444, 2007.
6. Tsai, W. T., Lee, M. K. and Chang, Y. M., “Fast
pyrolysis of rice husk: Product yields and
compositions”, Bioresource Technology, 98 (1):
22-28, 2007.
7. Basu, P., “Biomass gasification and pyrolysis
practical design and theory”, Academic Press is an
imprint of Elsevier, USA, 75-78, 2010.
8. Nilsen, M. H., Antonakou, E., Bouzga, A.,
Lappas, A., Mathisen, K. and Stöcker, M.,
“Investigation of the effect of metal sites in Me-Al-
MCM-41 (Me=Fe, Cu or Zn) on the catalytic
behavior during the pyrolysis of wooden based
biomass”, Microporous and Mesoporous
Materials, 105 (1-2): 189-203, 2007.
9. Nakai, T., Kartal, S. N., Hata, T. and Imamura, Y.,
“Chemical characterization of pyrolysis liquids of
wood-based composites and evaluation of their
bio-efficiency”, Building and Environment, 42
(3): 1236-1241, 2007.
10. Şensöz, S., Angın, D. ve Demiral, İ., “Kızılçam
odun kabuğunun pirolizi ve ürünlerinin
incelenmesi”, Yenilebilir Enerji Kaynakları
Sempozyumu, İzmir, 147-151, 2001.
11. Gerçel, H. F., “Bio-oil production from
Onopordum acanthium L. by slow pyrolysis”,
Journal of Analytical and Applied Pyrolysis, 92
(1): 233-238, 2011.
12. Heo, S. H., Park, H. J., Park, Y.-K., Ryu, C., Suh,
D. J., Suh, Y.-W., Yim, J.-H. and Kim, S.-S.,
“Bio-oil production from fast pyrolysis of waste
furniture sawdust in a fluidized bed”,
Bioresource Technology, 101 (1): 91-96, 2010.
13. American Society for Testing and Materials,
“Standard test method for direct moisture content
measurement of wood and wood-base materials”,
ASTM Standards D 4442-92, Easton, M. D.,
USA, 1997.
14. American Society for Testing and Materials,
“Standard test method for volatile matter in
analysis sample refuse derived fuel”, ASTM
Standards E-897-88, Easton, M. D., USA, 2004.
15. American Society for Testing and Materials,
“Standard test method for ash in wood”, ASTM
Standards D-1102-84, Easton, M. D., USA,
1983.
16. Rowell, R. M., Pettersen, R., Han, J. S., Rowell, J.
S. and Tshabalala, M. A., “Handbook of wood
chemistry and wood composites”, CRC Press,
487, 2005.
17. Wise, L. E. and John, E. C., “Wood chemistry”,
Reinhold Publication Co, New York, U.S.A., 1-
2: 1330, 1952.
18. Technical Association of the Pulp and Paper
Industry, “Acid-insoluble lignin in wood and
pulp”, TAPPI T 222 om-02, Tappi Pres, Atlanta,
GA, U.S.A., 2002.
19. Technical Association of the Pulp and Paper
Industry, “Solvent extractives of wood and pulp”,
Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi A. Özçifçi, G. Özbay
Gazi Üniv. Müh. Mim. Fak. Der. Cilt 28, No 3, 2013 479
TAPPI T 204 cm-97, Tappi Pres, Atlanta, GA,
USA, 1997.
20. Wang, Z., Cao, J. and Wang, J., “Pyrolytic
characteristics of pine wood in a slowly heating
and gas sweeping fixed-bed reactor”, Journal of
Analytical and Applied Pyrolysis, 84 (2): 179-
184, 2009.
21. Fagbemi, L., Khezami, L. and Capart, R.,
“Pyrolysis products from different biomasses:
Application to the thermal cracking of tar”,
Applied Energy, 69 (4): 293-306, 2001.
22. Liaw, S.-S., Wang, Z., Ndegwa, P., Frear, C., Ha,
S., Li, C.-Z. and Garcia-Perez, M., “Effect of
pyrolysis temperature on the yield and properties
of bio-oils obtained from the auger pyrolysis of
Douglas Fir Wood”, Journal of Analytical and
Applied Pyrolysis, 93: 52-62, 2012.
23. Erşen, T. ve Pehlivan, D., “Yüksek yoğunluklu
polietilen–odun karışımlarının birlikte pirolizi”, J.
Fac. Eng. Arch. Gazi Univ., 26, (3): 607-612,
2011.
24. Aho, A., Kumar, N., Eränen, K., Salmi, T., Hupa,
M. and Murzin, D. Y., “Catalytic pyrolysis of
woody biomass in a fluidized bed reactor:
Influence of the zeolite structure”, Fuel, 87 (12):
2493-2501, 2008.
25. Zhong, C. and Wei, X., “A comparative
experimental study on the liquefaction of wood”,
Energy, 29 (11): 1731-1741, 2004.
26. Savage, P. E., Levine, R. B., and Huelsman, C.
M.,“Hydrothermal processing of biomass”,
Thermochemical Conversion of Biomass to Liquid
Fuels and Chemicals, Edited by Mark Crocker,
The Royal Society of Chemistry, Cambridge,
UK., 1: 192-220, 2010.
27. Qi, Z., Jie, C., Tiejun, W. and Ying, X., “Review
of biomass pyrolysis oil properties and upgrading
research”, Energy Conversion and
Management, 48 (1): 87-92, 2007.
28. Branca, C., Giudicianni, P. and Di Blasi, C., “GCMS
characterization of liquid generated from lowtemperature
pyrolysis of wood”, Industrial &
Engineering Chemistry Research, 42 (14):
3190-3202, 2003.
29. Ingemarsson, A., Nilsson, U., Nilsson, M.,
Pedersen, J. R. and Olsson, J. O., “Slow pyrolysis
of spruce and pine samples studied with GC/MS
and GC/FTIR/FID”, Chemosphere, 36 (14):
2879-2889, 1998.
30. Zeitsch, K. J. “Applications of Furfural”, The
chemistry and technology of furfural and its many
by-products, Elsevier publication, Netherlands,
98-103, 2000.
31. Lu, Q., Wang, Z., Dong, C., Zhang, Z., Zhang, Y.,
Yang, Y. and Zhu, X., “Selective fast pyrolysis of
biomass impregnated with ZnCl2: Furfural
production together with acetic acid and activated
carbon as by-products”, Journal of Analytical
and Applied Pyrolysis, 91 (1): 273-279, 2011.
32. Colombini, M. P., Orlandi, M., Modugno, F.,
Tolppa, E.-L., Sardelli, M., Zoia, L. and Crestini,
C., “Archaeological wood characterisation by
PY/GC/MS, GC/MS, NMR and GPC techniques”,
Microchemical Journal, 85 (1): 164-173, 2007.
33. Özbay, G., “Odun ve Odun Esaslı Kompozit
Malzeme Talaşlarının Termal ve Katalitik Piroliz
Yöntemi ile Sıvılaştırılması”, Doktora Tezi,
Karabük Üniversitesi Fen Bilimleri Enstitüsü,
Karabük, 89-95, 2012.
34. López, D., Acelas, N. and Mondragón, F.,
“Average structural analysis of tar obtained from
pyrolysis of wood”, Bioresource Technology,
101 (7): 2458-2465, 2010.

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