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NOHUT SAMANI TARLA ATIĞININ SULU ÇÖZELTİLERDEN METİLEN MAVİSİ GİDERİMİNDE DÜŞÜK MALİYETLİ BİYOSORBENT OLARAK DEĞERLENDİRİLMESİ

EVALUATION OF FIELD DEBRIS OF CHICKPEA HUSK AS A LOW-COST BIOSORBENT FOR REMOVAL OF METHYLENE BLUE FROM AQUEOUS SOLUTIONS

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Abstract (2. Language): 
In the present study, an important agricultural waste, chickpea straw, was evaluated as biosorbent material for the removal of basic dyes from aqueous solutions. Effects of solution pH, biosorbent dosage, initial dye concentration, contact time and solution temperature on biosorption process were investigated. In addition, equilibrium, kinetic and thermodynamic studies were carried out for the methylene blue biosorption. It was determined that equilibrium data were in accordance with Freundlich isotherm and pseudo second order kinetic model was the best model to express the biosorption kinetics. Calculated thermodynamic parameters showed that, biosorption was a spontaneous endothermic process between 20 and 50 °C. The maximum monolayer biosorption capacity of chickpea husk was determined as 108.7 mg/g for methylene blue biosorption. As a result, chickpea straw could be used as an environmentally friendly, cheap and effective biosorbent material for the removal of methylene blue from aqueous solutions.
Abstract (Original Language): 
Yapılan bu çalışmada tarımsal bir atık olan nohut samanı, sulu çözeltilerden boyar madde gideriminde biyosorbent olarak değerlendirilmiştir. Çözelti pH’ı, biyosorbent miktarı, başlangıç boyar madde derişimi, temas süresi ve çözelti sıcaklığının biyosorpsiyon işlemine olan etkileri incelenmiştir. Ayrıca, metilen mavisi biyosorpsiyonuna ait denge izoterm, termodinamik ve kinetik çalışmalar gerçekleştirilmiştir. Biyosorpsiyon denge verilerinin Freundlich izotermi ile uyumlu olduğu belirlenmiş, biyosorpsiyonu en iyi ifade edebilen kinetik modelin ise sözde(yalancı) ikinci dereceden model olduğu saptanmıştır. Hesaplanan termodinamik parametreler, biyosorpsiyonun 20-50 °C aralığında kendiliğinden gerçekleşen endotermik bir işlem olduğunu göstermiştir. Metilen mavisi biyosorpsiyonu için nohut samanının maksimum tek tabaka biyosorpsiyon kapasitesi 108,7 mg/g olarak belirlenmiştir. Sonuç olarak, nohut samanının sulu çözeltilerden metilen mavisi gideriminde çevreye dost, düşük maliyetli ve etkili bir biyosorbent olarak kullanılabileceği belirlenmiştir.
717
726

REFERENCES

References: 

1. Doğan, M., Abak, H. ve Alkan, M., “Adsorption
of Methylene Blue onto Hazelnut Shell:
Kinetics, Mechanism and Activation
Parameters”, Journal of Hazardous Materials,
Cilt 164, 172-181, 2009.
2. Gökkuş, Ö. ve Çiner, F., “Dispers Sarı 119 Ve
Dispers Kırmızı 167 İçeren Atıksuların Fenton
Oksidasyon Prosesi İle Renk ve KOI
Giderimlerinin İncelenmesi”, Journal of the
Faculty of Engineering and Architecture of
Gazi University, Cilt 25, No 1, 49-55, 2010.
3. Aroguz, A.Z., Gulen, J. ve Evers, R.H.,
“Adsorption of Methylene Blue form Aqueous
Solution on Pyrolyzed Petrified Sediment”,
Bioresource Technology, Cilt 99, 1503-1508,
2008.
4. Aksu, A., Murathan, A. ve Koçyiğit, H.,
“Reaktif Mavi 221’in Pomza ile Adsorpsiyoın
Kinetiği”, Journal of the Faculty of
Engineering and Architecture of Gazi
University, Cilt 26, No 4, 807-812, 2011.
5. Murathan, A. ve Koçyiğit, H., “Sulu
Çözeltilerden Kadmiyum İyonlarının Dolgulu
Yataklarda At Kestanesi ve Meşe Palamudu
Kullanılarak Giderilmesi”, Journal of the
Faculty of Engineering and Architecture of
Gazi University, Cilt 28, No 2, 303-306, 2013.
6. Türkiye Cumhuriyeti Başbakanlık Yatırım
Destek ve Tanıtım Ajansı, “Türkiye Tarım
Sektörü Raporu”, Temmuz 2010,
Nohut Samanı Tarla Atığının Sulu Çözeltilerden Metilen Mavisi… M.Kılıç ve Ark.
Gazi Üniv. Müh. Mim. Fak. Der. Cilt 29, No 4, 2014 725
http://www.invest.gov.tr/trTR/infocenter/publica
tions/Documents/TARIM.SEKTORU.PDF
7. Food and Agriculture Organisation of United
Nations(FAO), “Tarım Ürünlerin Dünya
İstatistikleri”, Aralık 2012, www.fao.org
8. Han, R., Zou, W., Yu, W., Cheng, S., Wang, Y.
ve Shi, J., “Biosorption of Methylene Blue from
Aqueous Solution by Fallen Phoenix Tree’s
Leaves”, Journal of Hazardous Materials, Cilt
141, 156-162,2007.
9. Ghaedi, M., Hajati, S., Barazesh, B., Karimi, F.,
Ghezelbash, G., “Saccharomyces cerevisiae for
the biosorption of basic dyes from binary
component systems and the high order derivative
spectrophotometric method for simultaneous
analysis of Brilliant green and Methylene blue”,
Journal of Industrial and Engineering
Chemistry, Cilt 19, 227–233, 2013.
10. Aksu, Z., Ertuğrul, S., Dönmez, G., “Methylene
Blue biosorption by Rhizopus arrhizus: Effect of
SDS(sodium dodecylsulfate) surfactant on
biosorption properties”, Chemical Engineering
Journal, Cilt 158, No 3, 474–481, 2010.
11. Han, R., Wang, Y., Han, P., Shi, J., Yang, J., Lu,
Y., “Removal of methylene blue from aqueous
solution by chaff in batch mode”, Journal of
Hazardous Materials, Cilt 137, No 1, 550–557,
2006.
12. Pavan, F.A., Lima, E.C., Dias, S.L.P.,
Mazzocato, A.C., “Methylene blue biosorption
from aqueous solutions by yellow passion fruit
waste”, Journal of Hazardous Materials, Cilt
150, No 3, 703–712, 2008.
13. Xiao, X., Luo, S., Zeng, G., Wei, W., Wan, Y.,
Chen, L., Guo, H., Cao, Z., Yang, L., Chen, J. ve
Xi, Q., “Biosorption of Cadmium by Endophytic
Fungus(EF) Microsphaeropsis Sp. LSE10
İsolated from Cadmium Hyperaccumulator
Solanum Nigrum L.”, Bioresource Technology,
Cilt 101, 1668-1674, 2010.
14. Al-Anber, Z.A., Al-Anber, M.A., Matouq, M.,
Al-Ayed, O., Omari, N.M., “Defatted Jojoba for
the removal of methylene blue from aqueous
solution: Thermodynamic and kinetic studies”,
Desalination, Cilt 276, No 1–3, 169–174, 2011.
15. Cherifi, H., Fatih, B., Salah, H., “Kinetic studies
on the adsorption of methylene blue onto vegetal
fiber activated carbons”, Applied Surface
Science, Cilt 282, 52–59, 2013.
16. Akkurt, F., Alıcılar, A., Şendil, O., “Sularda
Bulunan Nitratın Adsorpsiyon Yoluyla
Uzaklaştırılması”, Journal of the Faculty of
Engineering and Architecture of Gazi
University, Cilt 17, No 4, 83-91, 2002.
17. Langmuir, I., “The Constitution and
Fundamental Properties of Solids and Liquids”,
Journal of American Chemical Society, Cilt
38, 2221-2295, 1916.
18. Freundlich, H.M.F., “Über die Adsorption in
Lösungen”, Zeitschrift für Physikalische
Chemie, Cilt 57, 385-470, 1906.
19. Dubinin, M.M. ve Radushkevich, L.V.,
“Equation of the Characteristic Curve of
Activated Charcoal”, Proceedings of the USSR
Academy of Sciences Physical Chemistry, Cilt
55, 331, 1947.
20. Lagergren, S., “Zur theorie der sogenannten
adsorption geloster stoffe”, Kungliga Svenska
Vetenskapsakademiens, Handlingar, Cilt 24,
1-39, 1898.
21. Ho, Y.S., McKay, G., “Pseudo-Second Order
Model for Sorption Process”, Process
Biochemistry, Cilt 34, 451-465, 1999.
22. Weber, W.J., Morriss, J.C., “Kinetics of
Adsorption on Carbon From Solution”, Journal
of the Sanitary Engineering Division
American Society of Civil Engineers, Cilt 89,
31-60, 1963.
23. Amini, M., Younesi, H., Bahramifar, N.,
“Biosorption of nickel(II) from aqueous solution
by Aspergillus niger: Response surface
methodology and isotherm study”,
Chemosphere, Cilt 75, No 11, 1483–1491,
2009.
24. Ferrero, F., “Dye Removal by Low Cost
Adsorbents: Hazelnut Shells in Comparison with
Wood Sawdust”, Journal of Hazardous
Materials, Cilt 142, 144-152, 2007.
25. Vadivelan, V., Vasanth Kumar K., “Equilibrium,
kinetics, mechanism, and process design for the
sorption of methylene blue onto rice husk”,
Journal of Colloid and Interface Science, Cilt
286, No 1, 90–100, 2005.
26. Batzias, F., Sidiras, D., Schroeder, E., Weber,
C., “Simulation of Dye Adsorption on
Hydrolyzed Wheat Straw in Batch and Fixed-
Bed Systems”, Chemical Engineering Journal,
Cilt 148,459-472, 2009.
27. Feng, Y., Yang, F., Wang, Y., Ma, L., Wu, Y.,
Kerr P.G., Yang, L., “Basic Dye Adsorption
onto an Agro-Based Waste Material-Sesame
Hull(Sesamum İndicum L.)”, Bioresource
Technology, Cilt 102, 10280-10285, 2011.
28. Belala. Z., Jeguirim, M., Belhachemi,M.,
Addoun, F., Trouvé, G., “Biosorption of Basic
Dye from Aqueous Solutions by Date Stones and
Palm-Trees Waste: Kinetic, Equilibrium and
Thermodynamic Studies”, Desalination, Cilt
271, 80-87, 2011.
29. Uddin, M.T., Islam, M.A., Mahmud, S.,
Rukanuzzaman, M., “Adsorptive Removal of
Methylene Blue by Tea Waste”, Journal of
Hazardous Materials, Cilt 164, 53-60, 2009.
30. Annadurai, G., Juang, R.S., Lee, D.J., “Use of
cellulose-based wastes for adsorption of dyes
from aqueous solutions”, Journal of Hazardous
Materials, Cilt 92, No 3, 263–274, 2002.
M.Kılıç ve Ark. Nohut Samanı Tarla Atığının Sulu Çözeltilerden Metilen Mavisi…
726 Gazi Üniv. Müh. Mim. Fak. Der. Cilt 29, No 4, 2014
31. Doğan, M., Özdemir, Y., Alkan, M.,
“Adsorption kinetics and mechanism of cationic
methyl violet and methylene blue dyes onto
sepiolite”, Dyes and Pigments, Cilt 75, Sayı 3,
701–713, 2007.
32. Hamayun, M., Mahmood, T., Naeem, A.,
Muska, M., Din, S.U., Waseem, M.,
“Equilibrium and kinetics studies of arsenate
adsorption by FePO4”, Chemosphere, Cilt 99,
207–215, 2014.
33. Huang, W.Y., Li, D., Liu, Z.Q., Tao, Q., Zhu,
Y., Yang, J., Zhang, Y.M., “Kinetics, isotherm,
thermodynamic, and adsorption mechanism
studies of La(OH)3-modified exfoliated
vermiculites as highly efficient phosphate
adsorbents”, Chemical Engineering Journal,
Cilt 236, 191–201, 2014.
34. Dursun, A.Y., “A comparative study on
determination of the equilibrium, kinetic and
thermodynamic parameters of biosorption of
copper(II) and lead(II) ions onto pretreated
Aspergillus niger”, Biochemical Engineering
Journal, Cilt 28, No 2, 187–195, 2006.

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