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Didecyl Dimethyl Ammonium Tetrafluoroborate (DBF) ve Didecyl Dimethyl Ammonium Chloride (DDAC) ile Emprenye Edilmiş Kontrplaklar: Mekanik Özellikler ve Biyolojik Direnç

Plywood Treated with Didecyl Dimethyl Ammonium Tetrafluoroborate (DBF) and Didecyl Dimethyl Ammonium Chloride (DDAC): Mechanical Properties and Biological Resistance

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Abstract (2. Language): 
This study evaluated decay and termite resistance of plywood panels treated with didecyl dimethyl ammonium tetrafluoroborate (DBF) and didecyl dimethyl ammonium chloride (DDAC) as quaternary ammonia compounds. Mechanical properties and bonding quality of treated plywood specimens were also tested. The modulus of rupture (MOR) values of both DBF- and DDAC-treated plywood specimens fulfilled minimum requirements for plywood F25-F30 (38-45 N/mmJ) set by the EN standards. The modulus of elasticity (MOE) of DDAC-treated plywood specimens decreased when compared with DBF-treated and untreated plywood specimens. The bonding quality values of all specimens did not meet the requirements set by the TS standards. The results suggest that DBF and DDAC may decrease mechanical properties by possible interaction with the glue and wood components depending on both chemical structure and retention levels in treated plywood specimens. Decay resistance tests showed that DBF-treated plywood specimens were more resistant against the fungi tested when compared with those of DDAC treated; however, both DBF and DDAC had no protective effect against termite attack.
Abstract (Original Language): 
Bu çalışma didecyl dimethyl ammonium tetrafluoroborate (DBF) ve didecyl dimethyl ammonium chloride (DDAC) ile emprenye edilmiş kontrplak levhaların mekanik özellikleri ile mantar ve termitlere karşı dayanıklılığını incelemektedir. Levha örneklerinin yarılma dirençlerinin (MOR) EN standardları tarafından belirlenen F25-F30 (38-45 N/mm2) limitlerden düşük olmadığı fakat elastikiyet modülü (MOE) değerlerinin DDAC ile emprenye edilen örneklerde DBF ye kontrol levhalarına karşılık azaldığı belirlenmiştir. Yapışma direnci değerlerinin ise TS standardları tarafından belirlenen limit değerlerinden düşük olduğu bulunmuştur. Böylece DBF ve DDAC emprenye maddelerinin, tutkal ve odun komponentleri arasında olası etkileşimlerden dolayı mekanik özellikleri olumsuz etkileyeceği belirlenmiştir. Ayrıca, DBF ile emprenye edilen levhaların DDAC ile korunanlara karşılık test edilen mantarlara karşı daha dayanıklı olduğu fakat her iki maddenin de termitlere karşı levhaları koruyamayacağı bulunmuştur.
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REFERENCES

References: 

Van Acker, J.C.R. and M.K.M. Stevens, 1993. Improvement in decay resistance of some commercial plywoods by waterborne and solvent-borne preservative treatments. In: Proceedings of IUFRO Symposium on the Protection of Wood-Based Composite Products. May 1993, Orlando, Florida, USA, pp. 88-92.
Akbulut, T.,
S.N
. Kartal and F. Green III, 2004. Properties of medium density fiberboard (MDF) treated with N'-N-(l, 8-Naphthalyl) hydroxylamine (NHA-Na), borax and boric acid. Forest Products Journal. 54 (10): 59-64.
Barnes, H.M. and T.L. Amburgey, 1993. Technologies for the protection of wood composites. In: Proceedings of IUFRO Symposium on the Protection of Wood-Based Composite Products. May 1993, Orlando, Florida, USA, pp. 7-11.
Curling, S.F. and R.J. Murphy, 1999. The effect of artificial ageing on the durability of wood-based boards materials against basidiomycete decay fungi. Wood Science and Technology. 33: 245-257.
EN 310., 1993. Wood-based panels. EN 310: Determination of bending strength and modulus of elasticity. European Committee for Standardization.
EN 636., 1996. Plywood-Specifications-Part 1: Requirements for plywood for use in dry conditions. European Committee for Standardization.
EN 314., 1993. Plywood-Bonding quality-Part 1: Test methods. European Committee for Standardization.
Gosselin RE, R.P. Smith, H.C. Hodge and J.E. Braddock, 1984. Clinical Toxicology
for Commercial Products. 5th Edition. Williams and Williams: Baltimore, MD. Hwang, W.J., S.N. Kartal, K. Shinoda, and Y. Imamura, 2005. Surface treatment for
preventing decay and termite attack in wood using didecyl dimethyl ammonium
tetrafluoroborate (DBF) incorporated with acryl-silicon type resin. Holz als Roh
und Werkstoff. 63: 204-208. Hwang, W.J., S.N. Kartal, Y. Imamura, K. Tsunoda and, K. Shinoda, 2007.
Comparative effectiveness of two alkylammonium compounds as wood
preservatives. Journal of Wood Science. 53: 332-338. Hwang, W.J., S.N. Kartal, T. Yoshimura and Y. Imamura, 2007. Synergistic effect
of heartwood extractives and quaternary ammonium compounds on termite
resistance of treated wood. J of Pest Management Science. 63: 90-95. Hwang, W.J., S.N. Kartal and Y. Imamura, 2006. Evaluation of new quaternary
ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) in
comparison with DDAC: Leachability and termite resistance tests. Holz als Roh
und Werkstoff 64: 111-116. JIS K 1571., 2004. Test methods for determining the effectiveness of wood
preservatives and their performance requirements (in Japanese). Japanese Standard
Association.
Kamdem, D.P., A. Pizzi and A. Jermennaud, 2002. Durability of heat-treated wood.
Holz als Roh und Werkstoff. 60:1-6. Kartal, S.N. and F. Green III, 2003. Leachability of boron from wood treated with
natural and semi-synthetic polymers and calcium precipitating agent. Holz als Roh
und Werkstoff. 61 (5): 388-389.
Plywood Treated with Didecyl Dimethyl Ammonium Tetrafluoroborate and Didecyl... 51
Kartal,
S.N.
, K. Shinoda and Y. Imamura, 2005. Laboratory evaluation of boron-containing quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) for inhibition of mold and stain fungi. Holz als Roh und Werkstoff. 63: 73-77.
Kartal,
S.N.
, W.J. Hwang, K. Shinoda and Y. Imamura, 2006. Laboratory evaluation of boron-containing quaternary ammonia compound didecyl dimethyl ammonium tetrafluoroborate (DBF) for control of decay and termite attack and fungal staining of wood. Holz als Roh und Werkstoff. 64 (1): 62-67.
Laks, P.E. and M.J. Manning, 1995. Preservation of wood composites with zinc borate. Doc. No. IRG/WP 95-30074. The Inter. Res. Group on Wood Preservation, Stockholm, Sweden.
Laks, P.E. and M.J. Manning, 1997. Mobility of zinc borate wood composite
preservative. IRG/WP 97-30153. International Research Group on Wood
Preservation, Stockholm, Sweden. Matejuk J.Z., E. Urbanik and J. Pernak, 2004. New bis-quaternary ammonium and
bis-imidazolium chloride wood preservatives. Holzforschung. 58: 292-299. Pernak J, J.Z. Matejuk, A. Kropacz and F. Flaczyk, 2004. Ionic liquids in wood
preservation. Holzforschung. 58: 286-291. Preston A.F., P.J. Walcheski, P.A. McKaig and D.D. Nicholas, 1987. Recent
research on alkylammonium compounds in the U.S. In: Proceedings, American
Wood Preservers'Association (AWPA) 83: 331-34. TS 4520., 1985. Kontrplak - Yapıda Kullanılan. Turk Standardlar Enstitüsü, Ankara. Tsunoda, K., H. Watanabe, K. Fukuda and K. Hagio, 2002. Effects of zinc borate on
the properties of medium density fiberboard. Fores Prod. J. 52 (11/12): 62-65.

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