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BİODİZELİN OKSİTLENME KARARLILIĞI ÜZERİNE DENEYSEL BİR ARAŞTIRMA

AN EXPERIMENTAL INVESTIGATION ON OXIDATIVE STABILITY OF BIODIESEL

Journal Name:

  • Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi

Publication Year:

  • 2004

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
Biodiesel is an alternative fuel for diesel engines that can be produced from renewable feed stocks such as vegetable oil and animal fats. These feed stocks are reacted with an alcohol to produce alkyl monoesters. The obtained ester can be used in conventional diesel engines with little or no modification. Biodiesel, especially if produced from highly unsaturated oils, oxidizes more rapidly than diesel fuel. This paper reports the results of accelerated oxidation tests on biodiesel. These tests show the impact of time, oxygen flow rate, temperature, metals, and feedstock type on the rate of oxidation. Blending with diesel fuel and the addition of antioxidants are also explored. The data indicate that without antioxidants, biodiesel will oxidize very quickly at temperatures typical of diesel engines. This oxidation results in increases in peroxide value, acid value, and viscosity. While the peroxide value generally reaches a plateau of about 350 meq O2/kg, the acid value and viscosity increase monotonically as oxidation proceeds.
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Abstract (Original Language): 
Biodizel, dizel motorları için hayvansal ve bitkisel yağlar gibi yenilenebilir kaynaklardan üretilen alternatif bir dizel yakıtıdır. Bitkisel ve hayvani yağlar, alkil mono esteri üretmek için bir alkol ile reaksiyona sokulur ve elde edilen ester, motor üzerinde hemen hemen hiç değişiklik yapılmadan kullanılabilir. Biodizel, yüksek oranlı doymamış yağlardan üretildiğinde, dizel yakıtından çok daha hızlı bir şekilde oksitlenir. Bu çalışmada, biodizelin hızlandırılmış oksitlenme test sonuçları sunulmuştur. Bu testler, zamanın, oksijen akış oranının, sıcaklığın, metallerin ve farklı biodizel hammaddelerinin, oksitlenme üzerine etkisini göstermektedir. Ayrıca üretilen biodizeller, motorinle karışım oluşturularak ve antioksidanlar ilave edilerek de incelenmiştir. Deneysel çalışmaların sonucu, normal dizel motor sıcaklıklarında antioksidan içermeyen biodizelin çok daha çabuk bir şekilde oksitlendiğini göstermektedir. Bu oksitlenme işleminde, peroksit, asit ve viskozite değerlerinde artış gözlemlenmiştir. Peroksit yaklaşık 350 meq O2/kg değerine ulaştıktan sonra sabit kalmakta, asit ve viskozite değeri ise periyodik olarak artmaktadır.
FULL TEXT (PDF): 
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  • Turkish

REFERENCES

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Mühendislik Bilimleri Dergisi 2004 10 (2) 157-167
166
Journal of Engineering Sciences 2004 10 (2) 157-167
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