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TALYUMUN SAĞLIĞA ETKİSİ, ÇEVRESEL KAYGI VE TALYUM TÜRLENMESİ

EFFECT OF THALLIUM ON HEALTH, ENVIRONMENTAL CONCERN AND THALLIUM SPECIATION

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Abstract (2. Language): 
Thallium has been identified to be an environmentally important element because of its toxic effects. Owing to the high toxicity of thallium, even slightly contamination has been found to cause severe damages, such as loss of hair, nervous disease, impaired vision and growth retardation. This compound is used in optical systems, low temperature thermometers, dye pigments, photoelectric cells, and chemical synthesis. Determination of trace amounts of thallium is of great importance because of its toxic nature and also its increasing industrial applications. The main sources of thallium pollution at present are cement production and fossil fuel combustion. Thallium can be found in two different oxidation states, Tl (I) and Tl (III). Although Tl (I) is more stable in aqueous solutions, Tl (III) forms complexes of greater stability. Therefore, the determination of chemical species in the environmental samples is important and it has considerably increased interest in the last few years.
Abstract (Original Language): 
Talyum zehirli etkilerinden dolayı çevresel olarak önemli bir element olarak tanımlanmaktadır. Talyumun yüksek zehirliliği nedeniyle çok düşük düzeyde bulaşması bile saç kaybı, sinir hastalıkları, görme zayıflığı, büyüme gecikmesi gibi ciddi hasarlara neden olabilmektedir. Bu bileşik optik sistemlerde, düşük sıcaklık termometrelerinde, boya pigmentlerinde, fotoelektrik hücrelerinde ve kimyasal sentezlerde kullanılır. Talyumun eser miktarını belirleme zehirli yapısı ve artan endüstriyel uygulamalarından dolayı büyük bir önem taşır. Günümüzde talyum kirliliğinin ana kaynakları çimento üretimi ve fosil yakıtların yanmasıdır. Talyum, Tl (I) ve Tl (III) olmak üzere iki farklı yükseltgenme basamağında bulunabilir. Tl (I) sulu çözeltilerde daha kararlı olmasına rağmen, Tl (III) daha kararlı kompleksler oluşturur. Bundan dolayı çevresel örneklerde kimyasal türlerin belirlenmesinin önemi son birkaç yılda hızla artmıştır.
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REFERENCES

References: 

[1] HABASHI, F,“Handbook of Extractive Metallurgy”, Volume II, WILEY-VCH, Germany, 1997.
[2] E, John, “The Elements”, Colarendun Press, Oxford, 1989.
[3] BALDWIN DR, MARSHALL WJ, “Heavy Metal Poisoning and Its Laboratory Investigation”, Annals of Clinical Biochemistry, 36, 267-300, 1999.
[4] www.health.net
[5] www.portfolio.mvm.ed.ac.uk
[6] www.kimyaevi.org
[7] SKOOG, D.A., HOLLER, F.J., NIEMAN, T.A., “Principles of Instrumental Analysis”, 5 th ed., Saunders, Philadelphia,1998.
[8] LIN, T.S., O. NRIAGU. O.J, “Thallium speciation in river waters with Chelex-100 resin”, Analytica Chimica Acta, 395, 301-307, 1999.
[9] ] LANA, C.H., LIN, T.S., “Acute toxicity of trivalent thallium compounds to Daphnia magna”, Ecotoxicology and Environmental Safety”, 61 432–435,2005.
[10] HOSSEINI, M.S., CHAMSAZ, M, RAISSI, H AND NASERI, Y., "Flotation Seperation and Electrothermal Atomic Absorption Spectrometric Determination of Thallium in Wastewater Samples”, Annali di Chimica by Societa Chimica Italiana, 2005; 96.
[11] VILLAR, M.,OALAVA, F., LAVILLA, I., and BENDICHO, C., “Operational speciation of thallium in environmental solid samples by electrothermal atomic absorption spectrometry according to the BCR sequential extraction scheme”, J. Anal. At. Spectrom., 2001; 16; 1424–1428.
[12] BATLEY, G. E.; Trace Element Speciation: Analytical methods and problems, CRC Press, Inc, USA, 1991.
[13] TOWNSHEND, A., “Trends and Developments in On-Line Preconcentration” 1. Ege Analitik Kimya Kongresi, İzmir, 18-20 Kasım 1998.
[14] CAVE, M.R BUTLER O., CHENERY, S.R.N., COOK, J. M., CRESSER M.S.AND MİLES, D.L. “Atomic Spectrometry Update. Environmental Analysis”, J.Anal.At.Spectrom, 16, 194-235, 2001.
[15] Eser Analiz (Kimyasal İz Analiz) Yaz Okulu, İzmir, 25-29 Haziran 2001.
[16] DE BEER, H. AND COETZEE, P. P. “Vanadium speciation by ion chromatography”, Fresenius’ Journal of Analytical Chemistry, 348, 806, 1994.
[17] CVETKOVIC, J, SONJA ARPADJAN, S., KARADJOVA, I, STAFILOV, T, “Determination of thallium in wine by electrothermal atomic absorption spectrometry after extraction preconcentration”, Spectrochimica Acta Part B, 57, 1101–1106, 2002.
[18] ENSAFIL A., AND. REZAEI, B., “Speciation of Thallium by Flow Injection Analysis with Spectrofluorimetric Detection”, Microchemical Journal, 60, 75–83,1998.
[19] www.inchem.org
[20] PETERA, A.L.,VIRARAGHAVANB, T., "Thallium: a review of public health and environmental concerns”, Environment International, 31, 493– 501, 2005.
[21] SONIA GALVAN-ARZATE, S.G., ANTAMARIA, A., “Thallium toxicity”, Toxicology Letters, 99, 1–13, 1998.
[22] ARABINDA K. DAS, A.K., DUTTA, M., CERVERA, L., GUARDIA, M., “Determination of thallium in water samples”, Microchemical Journal, 86, 2–8, 2007.

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