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BAZI YENİ DİNÜKLEER BAKIR(II) SCHİFF BAZI KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

SYNTHESIS AND CHARACTERIZATION OF SOME NOVEL DINUCLEAR COPPER(II) SCHIFF BASE COMPLEXES

Journal Name:

  • Süleyman Demirel Üniversitesi Fen Dergisi

Publication Year:

  • 2008

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
In this study, four novel homo- and heterodinuclear copper(II) complexes were synthesized by the addition of metal salts of copper(II), manganese(II), cobalt(II) and nickel(II) to the mononuclear copper(II) Schiff base complex. Synthesized all complexes were characterized by elemental analyses, magnetic susceptibility, molar conductivity, FT-IR and ICP-OES studies. Elemental analyses, stoichiometric and spectroscopic data of the metal complexes indicated that the metal:ligand ratio of dinuclear copper(II) complexes were found to be 2:1 and those Cu(II) ions are coordinated to the nitrogen atoms of the Schiff bases and oximes.
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Abstract (Original Language): 
Bu çalışmada. mononükleer bakır(II) Schiff bazı kompleksine bakır(II), mangan(II), kobalt(II) ve nikel(II) metal tuzlarının ilavesiyle dört yeni homo- ve heterodinükleer bakır(II) kompleksi sentezlenmiştir. Sentezlenen tüm komplekslerin yapıları elementel analiz, manyetik sussebtibilite, molar iletkenlik, FT-IR ve ICP-OES çalışmalarıyla aydınlatılmıştır. Metal komplekslerin elementel analiz, stokiyometrik ve spektroskopik verileri, dinükleer bakır(II) komplekslerde metal:ligand oranının 2:1 olduğunu ve bu komplekslerde bakır(II) iyonlarının Schiff bazları ve oksimlerdeki azot atomlarıyla koordinasyona girdiğini göstermiştir.
FULL TEXT (PDF): 
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  • 1
42-50
  • Turkish

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