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[M(1(2H)-phthalazinone)n.Cl2] (M = Co, Cu and Mn; n = 1, 2) Bileşiklerinin Kırmızıaltı ve Mikroraman Spektroskopisi ile İncelenmeleri

Infrared and Micro-Raman Spectroscopic Studies of [M(1(2H)-phthalazinone)n.Cl2] (M = Co, Cu and Mn; n = 1, 2) Complexes

Journal Name:

  • Süleyman Demirel Üniversitesi Fen Dergisi

Publication Year:

  • 2012

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
In this study, the Co(II)' Cu(II) and Mn(II) metal halide complexes of 1(2H)-phthalazinone were characterized by elemental analysis, FT-IR and micro-Raman spectroscopies. The M(1(2H)-phthalazinone)n.Cl2 (M = Co, Cu and Mn; n = 1, 2) complexes have been prepared for the first time and their vibrational wavenumbers were reported. The results obtained experimentally indicate that the coordination between 1(2H)-phthalazinone and different metal ions gives different metal-oxygen stretching frequencies which decrease in the following order Co(II) > Mn(II) > Cu(II).
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Abstract (Original Language): 
Bu çalışmada, 1(2H)-fitalazinon Co(II), Cu(II) ve Mn(II) metal halid bileşikleri, elemental analiz, FT-IR ve mikro-Raman spektroskopileri ile karakterize edilmiştir. M(1(2H)-fitalazinon)n.Cl2 (M = Co, Cu ve Mn; n = 1, 2) bileşikleri ilk kez hazırlanmıştır ve titreşim dalgasayıları sunulmuştur. Deneysel olarak elde edilen sonuçlar, 1(2H)-fitalazinon ile metal iyonları arasındaki koordinasyonun, Co(II) > Mn(II) > Cu(II) olarak azalan metal-oksijen gerilme frekanslarını verdiğini göstermektedir.
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REFERENCES

References: 

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N. Öztürk, S. Bahçeli
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Nuri Öztürk
e-mail:
nuriozturk@sdu. edu. tr

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