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ASETİK ASİ TİN ETİL ALKOL İLE KATALİTİK REÇİNE KATALİZÖRLÜĞÜNDE ESTERLEŞME KİNETİĞİ

KINETIC OF ESTERIFICATION OF ETHYL ALCOHOL BY ACETIC ACID ON A CATALYTIC RESIN

Journal Name:

  • Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi

Publication Year:

  • 2002

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
The conversion kinetics of diluted acetic acid to ethyl acetate by ethanol esterification in a batch reactor in liquid phase with an acidic polymer catalyst (lewatit series) was studied. The intrinsic rate constants have been correlated with the reaction temperature, concentration of catalyst, initial ratios of reactants and initial water concentrations. The kinetic analysis was restricted to the system at hand in which a liquid and vapor phase are at equilibrium.
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Abstract (Original Language): 
Seyreltik asetik asit çözeltilerinin asidik gruplu polimerik reçine katalizörlüğünde etil alkol ile esterleşme reaksiyonu kesikli bir reaktörde gerçekleştirilmiştir. Reaksiyon kinetiği üzerine sıcaklık, başlangıçtaki reaktanların mol oranları, başlangıçtaki su konsantrasyonu ve katalizör konsantrasyonu etkileri incelenmiştir. Kesikli reaktörde sıvı ve buhar fazlarının hızla dengeye ulaşmasının reaksiyon kinetiğini sınırladığı belirlenmiştir.
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