Buradasınız

Anasayfa » Content

PROPİYONİK ASİT-SU-ÇÖZÜCÜ (n-AMİL ALKOL VE n-AMİL ASETAT) ÜÇLÜ SİSTEMLERİNİN SIVI-SIVI DENGELERİ

LIQUID-LIQUID EQUILIBRIA OF THE TERNARY SYSTEMS PROPIONIC ACID - WATER - SOLVENT (n-AMYL ALCOHOL AND n-AMYL ACETATE)

Journal Name:

  • Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi

Publication Year:

  • 2005

Key Words:

Keywords (Original Language):

Author NameUniversity of AuthorFaculty of Author
Abstract (2. Language): 
The experimental liquid-liquid equilibrium (LLE) data have been obtained at 25 oC for ternary systems propionic acid-water-«-amyl alcohol and propionic acid-water-«-amyl acetate. The reliability of the experimental tie line data are checked using the methods of Othmer-Tobias and Hand. The distribution coefficients and separation factors were obtained from experimental results and are also reported. The predicted tie line data obtained by UNIFAC method are compared with experimental data. It is concluded that «-amyl alcohol and «-amyl acetate are suitable separating agents for dilute aqueous propionic acid solutions.
Bookmark/Search this post with
Abstract (Original Language): 
Propiyonik asit-su-«-amil alkol ve propiyonik asit-su-«-amil asetat üçlü sistemlerine ait sıvı-sıvı dengeleri 25 oC'de izotermal şartlarda incelenmiştir. Elde edilen bağlantı doğrusu verilerinin doğruluğu Othmer-Tobias ve Hand korelasyonları kullanılarak test edilmiştir. Deneysel verilerden yararlanarak dağılma katsayıları ve ayırma faktörleri hesaplanmıştır. İncelenen her bir sisteme ait denge verileri, UNIFAC metodu ile de hesaplanmıştır. Deneysel denge verileri ve UNIFAC metodu ile bulunan veriler karşılaştırmalı olarak sunulmuştur. Deneysel veriler değerlendirildiğinde «-amil alkol ve «-amil asetat'ın propiyonik asitin sulu çözeltilerinden ekstraksiyonla geri kazanımında, çözücü olarak kullanılabileceği söylenebilir.
FULL TEXT (PDF): 
PDF icon arastirmax-propiyonik-asit-su-cozucu-n-amil-alkol-n-amil-asetat-uclu-sistemlerinin-sivi-sivi-dengeleri.pdf
  • 2
293
300
  • Turkish

REFERENCES

References: 

Alders, L. 1959. Liquid-liquid Extraction, 2nd Ed., Elsevier, Amsterdam.
Arce, A., Blanco, A., Sauza, P. and Vidal, I. 1995. Liquid-Liquid Equilibria of the Ternary Mixtures Water + Propanoic Acid + Methyl Ethyl Ketone and Water + Propanoic Acid + Methyl Propyl Ketone, J. Chem. Eng. Data, 40, 225-229.
Arce, A., Blanco, A., Sauza, P. and Vidal, I. 1993. Liquid-Liquid Equilibria of the Ternary System Water + Propanoic Acid + Methyl Isobutyl Ketone at Various Temperatures, J. Chem. Eng. Data, 38,
201-203.
Brandani, V., Chianese, A. and Rossi, M. 1985. Ternary Liquid-Liquid Equilibrium Data for the Water-Ethanol-Benzene System, J. Chem. Eng.
Data, 30, 27.
Cehreli, S. 2002. Liquid-Liquid Equilibria of the Acetic Acid-Water-Mixed Solvent (Cyclohexyl Acetate-Cyclohexanol) System, Braz. J. Chem. Eng., 19 (01), 45-53.
Cehreli, S., Tatlı,
B
. and Dramur, U. 1999. Liquid-Liquid Equilibria of Water-Propionic Acid-Solvent (n-Butyl Acetate, Propyl Acetate and Isopropyl Acetate) Ternaries, Chimica Acta Turcica, 27 (2),
53-61.
Colombo, A., Battilana, P., Ragaini, V., Bianchi, C. L. 1999. Liquid-Liquid Equilibria of the Ternary Systems Water+Acetic Acid+Ethyl Acetate and Water+Acetic Acid+Isophorone (3, 5, 5-Trimethyl-2-cyclohexen-1-one), J. Chem. Eng. Data. 44, 35¬39.
Daubert, T. E. 1987. Chemical Engineering Thermodynamics, Second ed., McGraw-Hill International Editions, ISBN 0-07-015413-9, Singapur.
Mühendislik Bilimleri Dergisi 2005 11 (2) 293-300
299
Journal of Engineering Sciences 2005 11 (2) 293-300
Propiyonik Asit-Su-Çözücü (n-Amil Alkol ve n-Amil Asetat) Üçlü Sistemlerinin Sıvı-Sıvı Dengeleri, D. Özmen
Dinçer, S. 1984. Kimya Mühendisliğinde Denge Süreçlerinin Termodinamiği, B.Ü. Yayınları, No: 319, İstanbul.
Dramur, U. and Tatlı, B. 1993. Liquid-Liquid Equilibria of Water+Acetic Acid+Phthalic Esters (Dimethyl Phthalate and Diethyl Phthalate)
Ternaries. J. Chem. Eng. Data. 38, 23-25.
Fandary, M.S.H., Aljimaz, A.S. and Al-Kandary, J.A. 1999. Liquid-Liquid Equilibria for the System Water+Ethanol+Ethyl tert-Butyl Ether, J. Chem. Eng. Data, 44, 1129-1131.
Fahim, M. A. Qader, A. and Hughes M. A. 1992. Extraction Equilibria of Acetic Acid and Propionic Acids from Dilute Aqueous Solution by Several
Solvents, Sep. Sci. Technol., 27 (13) 1809-1821.
Kyle, B.G. 1992. Chemical and Process Thermodynamics, Second ed., Prentice Hall, Englewood Cliffs, ISBN 0-13-130030-X, New Jersey.
Lo, T.C., Baird, M.H.I., Hanson, C. 1991.
Handbook of Solvent Extraction, Second Ed., Krieger Publishing Co., Florida, ISBN 0-89464¬546-3
Othmer, T. F. and Tobias, P.E., 1942. Tie Line
Correlation, Ind. Eng. Chemistry, 34 (6), 693-696.
Ozmen, D., Dramur, U., and Tatlı, B. 2004. Liquid-Liquid Equilibria of Propionic Acid- Water-Solvent
(n-Hexane, Cyclohexane, Cyclohexanol and Cyclohexyl Acetate), Braz J Chem Eng 21 (4): 647¬657 OCT-DEC 2004.
Radwan, G.M., Al Muhtaseb, S.A. 1997. Phase
Equilibria of The Ternary System Water + Propionic Acid +2-Butanol, Separation Science and
Technology, 32 (8), 1463-1476.
Reid, R.C., Prausnitz, J.M., Poling, B.E. 1987. The Properties of Gases and Liquids, Fourth Ed., McGraw-Hill Inc., ISBN 0-07-051799-1, Mexico.
Sölimo,
H.N.
, Bonatti, C.M., Zurita, J.L. and Gramajo de Doz, M.B. 1997. Liquid-Liquid Equilibria for the System Water + Propionic Acid + 1-Butanol at 303.2 K. Effect of Addition of Sodium Chloride, Fluid Phase Equilibria, 137, 163-172.
Weast, R.C. (Editor), 1989-1990. Handbook of Chemistry and Physics, 70th Ed., CRC Press, Boca Raton, Florida.
Yoshizawa, H., Uemura, Y., Kawano, Y. and Hatate, Y. 1994. Equilibrium of Aqueous Propionic Acid with Trioctylamine in Dodecane, J. Chem.
Eng. Data, 39, 777-780.
Zurita, J.L., Gramajo de Doz, M.B., Bonatti, C.M. and Sölimo, H.N. 1998. Effect of Addition of Calcium Chloride on the Liquid-Liquid Equilibria of the Water + Propionic Acid + 1-Butanol System at 303.15 K., J. Chem. Eng. Data, 43, 1039-1042.

Thank you for copying data from http://www.arastirmax.com