Journal Name:
- International Journal of Energy Applications and Technologies
Key Words:
Author Name | University of Author | Faculty of Author |
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Abstract (2. Language):
The metal complexes of dicarboxylic acid derivatives were synthesized and their gas-storage
properties were characterized. Metal complexes displaying various metal-organic frameworks with 4,5-
imidazole-dicarboxylic acid ligand (L) with Mo(III), W(VI), Ce (III), Sm (III), and Sn (IV) were synthesized
in order to examine their gas adsorption properties. The porous complexes were characterized by
elemental analysis, FT-IR, 1H-NMR, spectroscopic methods and microanalysis. Investigation of the
structures of these complexes indicates that gases are most probably occluded in homogeneous and
linear micropores which are composed of micropore units surrounded by dicarboxylate bridges. Gas
storage and adsorption properties of these complexes were investigated via BET measurements.
Sorption property of H2 and N2 was performed at temperature of 298 K and pressure of 1 bar.
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